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Cited by 269

The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.

A Coordination Network That Catalyzes O2-Based Oxidations

Han, Jong Woo, Hill, Craig L.·2007·Journal of the American Chemical Society

Abstract

Reaction of Tb(III) and two bridging ligands, a redox-active benzoic acid-terminated hexavandate ([V 6 O 13 {(OCH 2 ) 3 C(4-CONHC 6 H 4 CO 2 H)} 2 ] 2- ( 1 ) and 4,4‘-bis(pyridine- N -dioxide) (bpdo) produces a catalytically active open-framework pillared layer-type coordination polymer, Tb1 . The network material catalyzes aerobic oxidation of PrSH to PrSSPr and the oxidation tetrahydrothiophene (THT) to tetrahydrothiophene oxide (THTO) by tert -butylhydroperoxide under ambient conditions. Tb(III) ions and bpdo units form two-dimensional (2D) coordination layers, and the 2D layers are connected by 1 to produce a three-dimensional coordination network. IR and powder X-ray diffraction of Tb1 before and after catalysis indicate the catalyst maintains an open framework structure during the catalytic reactions.

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Metadata

Authors
Han, J. W., & Hill, C. L.
Venue
Journal of the American Chemical Society
Published
2007-11-17
Volume
129
Issue
49
Pages
15094-15095
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1978137311
Cited by
269
References
7
FWCI
15.40
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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