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Glutathione- and Cysteine-Induced Transverse Overgrowth on Gold Nanorods
Abstract
We have demonstrated glutathione- and cysteine-induced transverse overgrowth on gold nanorods. In aqueous solutions, glutathione and cysteine are preferentially bound to the ends of gold nanorods that are stabilized by a cationic surfactant bilayer. This preferential end binding blocks the growth of the nanorods in the longitudinal direction completely and allows for the growth only in the transverse direction. As a result, the diameters of the nanorods become larger and larger while their lengths remain unchanged, as more and more gold precursor is supplied. In addition, the shape of the nanorods undergoes a gradual change from rods, peanuts, and truncated octahedra to faceted spheres during overgrowth. We believe that this transverse overgrowth provides an alternative means for tailoring the longitudinal plasmon wavelengths and extinction cross sections of gold nanoparticles and will therefore facilitate their use in optics, optoelectronics, and biotechnology.
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Cited by
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Shape Control of Colloidal Metal Nanocrystals
Tao, A. R., Habas, S., & Yang, P. (2008) · Small · doi:10.1002/smll.200701295 · Cited by 2,408
Shape control in gold nanoparticle synthesis
Grzelczak, M., Pérez-Juste, J., Mulvaney, P., & Liz-Marzán, L. M. (2008) · Chemical Society Reviews · doi:10.1039/b711490g · Cited by 1,911
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Sau, T. K., & Rogach, A. L. (2010) · Advanced Materials · doi:10.1002/adma.200901271 · Cited by 905
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Nehl, C. L., & Hafner, J. H. (2008) · Journal of Materials Chemistry · doi:10.1039/b714950f · Cited by 493
Vigderman, L., & Zubarev, E. R. (2013) · Chemistry of Materials · doi:10.1021/cm303661d · Cited by 414
Ordered Gold Nanostructure Assemblies Formed By Droplet Evaporation
Ming, T., Kou, X., Chen, H., Wang, T., Tam, H., Cheah, K., Chen, J., & Wang, J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803642 · Cited by 285
Self-citationSingle metal nanoparticles: optical detection, spectroscopy and applications
Zijlstra, P., & Orrit, M. (2011) · Reports on Progress in Physics · doi:10.1088/0034-4885/74/10/106401 · Cited by 283
Yuan, Q., & Wang, X. (2010) · Nanoscale · doi:10.1039/c0nr00342e · Cited by 63
Metadata
- Authors
- Kou, X., Zhang, S., Yang, Z., Tsung, C.-K., Stucky, G. D., Sun, L., Wang, J., & Yan, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-27
- Volume
- 129
- Issue
- 20
- Pages
- 6402-6404
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2082893863
- Cited by
- 195
- References
- 0
- FWCI
- 10.44
- Type
- journal article
- Language
- en
- Open access
- closed
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