The DOI matches its Crossref record.
Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes
Abstract
Linear copolymers of ethylene and acrylonitrile were prepared using palladium complexes bearing phosphine-sulfonate bidentate ligands. Acrylonitrile units located in the linear polyethylene backbones were detected for the first time by 13 C NMR spectroscopy. Catalyst systems employing isolated palladium complexes such as 3 showed much higher activity for the copolymerization than the in situ generation procedures, and molecular weight of the copolymers and acrylonitrile incorporation were dependent on the palladium complexes. Obtained linear copolymers of ethylene and acrylonitrile melt at higher temperature than branched copolymers.
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Citations
Cited by
Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts
Chen, E. Y.-X. (2009) · Chemical Reviews · doi:10.1021/cr9000258 · Cited by 573
Synthesis of functional ‘polyolefins’: state of the art and remaining challenges
Franssen, N. M. G., Reek, J. N. H., & de Bruin, B. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60032g · Cited by 485
Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts
Chen, Z., & Brookhart, M. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00225 · Cited by 405
Carrow, B. P., & Nozaki, K. (2014) · Macromolecules · doi:10.1021/ma500034g · Cited by 265
Self-citationAldehyde End‐Capped Degradable Polyethylenes From Hydrogen‐Controlled Ethylene/CO Copolymerization
Song, C., Yang, D., Wang, C., Tang, Z., Long, Y., Zhang, Y., & Jian, Z. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202410885 · Cited by 29
Shi, X.-C., & Jin, G.-X. (2012) · Organometallics · doi:10.1021/om3007568 · Cited by 27
Metadata
- Authors
- Kochi, T., Noda, S., Yoshimura, K., & Nozaki, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-27
- Volume
- 129
- Issue
- 29
- Pages
- 8948-8949
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2069551259
- Cited by
- 270
- References
- 0
- FWCI
- 10.90
- Type
- journal article
- Language
- en
- Open access
- closed
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