The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Hydrogen Generation from Weak Acids: Electrochemical and Computational Studies of a Diiron Hydrogenase Mimic
Abstract
Extended investigation of electrocatalytic generation of dihydrogen using [(mu-1,2-benzenedithiolato)][Fe(CO)3]2 has revealed that weak acids, such as acetic acid, can be used. The catalytic reduction producing dihydrogen occurs at approximately -2 V for several carboxylic acids and phenols resulting in overpotentials of only -0.44 to -0.71 V depending on the weak acid used. This unusual catalytic reduction occurs at a potential at which the starting material, in the absence of a proton source, does not show a reduction peak. The mechanism for this process and structures for the intermediates have been discerned by electrochemical and computational analysis. These studies reveal that the catalyst is the monoanion of the starting material and an ECEC mechanism occurs.
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Cites
te Velde, G., Bickelhaupt, F. M., Baerends, E. J., Fonseca Guerra, C., van Gisbergen, S. J. A., Snijders, J. G., & Ziegler, T. (2001) · Journal of Computational Chemistry · doi:10.1002/jcc.1056 · Cited by 10,152
Cited by
Thoi, V. S., Sun, Y., Long, J. R., & Chang, C. J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35272a · Cited by 668
Capon, J.-F., Gloaguen, F., Pétillon, F. Y., Schollhammer, P., & Talarmin, J. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.10.020 · Cited by 313
Wen, F., & Li, C. (2013) · Accounts of Chemical Research · doi:10.1021/ar300224u · Cited by 285
Singh, W. M., Baine, T., Kudo, S., Tian, S., Ma, X. A. N., Zhou, H., DeYonker, N. J., Pham, T. C., Bollinger, J. C., Baker, D. L., et al. (2012) · Angewandte Chemie · doi:10.1002/ange.201200082 · Cited by 66
Metadata
- Authors
- Felton, G. A. N., Vannucci, A. K., Chen, J., Lockett, L. T., Okumura, N., Petro, B. J., Zakai, U. I., Evans, D. H., Glass, R. S., & Lichtenberger, D. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-26
- Volume
- 129
- Issue
- 41
- Pages
- 12521-12530
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2041864511
- Cited by
- 361
- References
- 1
- FWCI
- 15.75
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
