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Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions

Obert, Edouard, Bellot, Mathilde, Bouteiller, Laurent, Andrioletti, Florence, Lehen-Ferrenbach, Catherine, Boué, François·2007·Journal of the American Chemical Society

Abstract

A new bis-urea based supramolecular polymer is reported and shown by viscosimetry, neutron scattering (SANS), and calorimetry (ITC) to self-assemble in a wide range of solvents, encompassing the polarity scale from water to toluene. The presence of both hydrogen-bonding and hydrophobic groups ensures that self-assembly occurs in water, aprotic polar solvents, and nonpolar solvents. Both the driving force for the assembly and the exact structure of the filaments is solvent dependent, but whatever the solvent, long rigid filaments are formed in dynamic equilibrium with the monomer.

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Metadata

Authors
Obert, E., Bellot, M., Bouteiller, L., Andrioletti, F., Lehen-Ferrenbach, C., & Boué, F.
Venue
Journal of the American Chemical Society
Published
2007-11-23
Volume
129
Issue
50
Pages
15601-15605
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2045840023
Cited by
179
References
0
FWCI
4.82
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions. https://app.cochat.ai/papers/10.1021/ja074296l
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Obert, E., Bellot, M., Bouteiller, L., Andrioletti, F., Lehen-Ferrenbach, C., & Boué, F. (2007). Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions. Journal of the American Chemical Society. https://doi.org/10.1021/ja074296l

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.