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Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions
Abstract
A new bis-urea based supramolecular polymer is reported and shown by viscosimetry, neutron scattering (SANS), and calorimetry (ITC) to self-assemble in a wide range of solvents, encompassing the polarity scale from water to toluene. The presence of both hydrogen-bonding and hydrophobic groups ensures that self-assembly occurs in water, aprotic polar solvents, and nonpolar solvents. Both the driving force for the assembly and the exact structure of the filaments is solvent dependent, but whatever the solvent, long rigid filaments are formed in dynamic equilibrium with the monomer.
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Citations
Cited by
Stimuli-responsive supramolecular polymeric materials
Yan, X., Wang, F., Zheng, B., & Huang, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35091b · Cited by 1,631
Krieg, E., Weissman, H., Shimoni, E., Bar On (Ustinov), A., & Rybtchinski, B. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503906p · Cited by 79
Metadata
- Authors
- Obert, E., Bellot, M., Bouteiller, L., Andrioletti, F., Lehen-Ferrenbach, C., & Boué, F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-23
- Volume
- 129
- Issue
- 50
- Pages
- 15601-15605
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2045840023
- Cited by
- 179
- References
- 0
- FWCI
- 4.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions. https://app.cochat.ai/papers/10.1021/ja074296l
- The paper
- Obert, E., Bellot, M., Bouteiller, L., Andrioletti, F., Lehen-Ferrenbach, C., & Boué, F. (2007). Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions. Journal of the American Chemical Society. https://doi.org/10.1021/ja074296l
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.