The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Considerations of Macromolecular Structure in the Design of Proton Conducting Polymer Membranes: Graft versus Diblock Polyelectrolytes
Abstract
Model fluorous−ionic copolymer systems were synthesized and studied to investigate the role of polymer architecture on morphology and properties of solid polymer electrolytes. Two types of compositionally similar but architecturally distinct copolymers were investigated: P(VDF- co -CTFE)- g - S PS graft copolymers, comprising a hydrophobic fluorous backbone and sulfonated styrene side chains, and P(VDF- co -HFP)- b - S PS diblock copolymers, comprising a hydrophobic fluorous segment linearly connected to a sulfonated styrenic segment. The macromolecular structure plays an important role in determining membrane morphology. Graft membranes possess a small ionic cluster morphology while diblock membranes possess a lamellar-like morphology. These morphological differences affect the threshold of ionic percolation, water sorption, proton mobility and concentration, proton conductivity, and anisotropy of ion conduction.
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Cites
On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells
Kreuer, K. D. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00632-3 · Cited by 2,969
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Cited by
Recent Development of Polymer Electrolyte Membranes for Fuel Cells
Zhang, H., & Shen, P. K. (2012) · Chemical Reviews · doi:10.1021/cr200035s · Cited by 1,361
Shin, D. W., Guiver, M. D., & Lee, Y. M. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00586 · Cited by 989
Ameduri, B. (2009) · Chemical Reviews · doi:10.1021/cr800187m · Cited by 830
Polymeric materials as anion-exchange membranes for alkaline fuel cells
Couture, G., Alaaeddine, A., Boschet, F., & Ameduri, B. (2011) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.04.004 · Cited by 685
Structure‐Morphology‐Property Relationships of Non‐Perfluorinated Proton‐Conducting Membranes
Peckham, T. J., & Holdcroft, S. (2010) · Advanced Materials · doi:10.1002/adma.201001164 · Cited by 622
Self-citationComb-shaped polymers to enhance hydroxide transport in anion exchange membranes
Li, N., Yan, T., Li, Z., Thurn-Albrecht, T., & Binder, W. H. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22050d · Cited by 375
Soboleva, T., Xie, Z., Shi, Z., Tsang, E., Navessin, T., & Holdcroft, S. (2008) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2008.05.017 · Cited by 264
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Metadata
- Authors
- Tsang, E. M. W., Zhang, Z., Shi, Z., Soboleva, T., & Holdcroft, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-16
- Volume
- 129
- Issue
- 49
- Pages
- 15106-15107
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2060051445
- Cited by
- 233
- References
- 2
- FWCI
- 17.32
- Type
- journal article
- Language
- en
- Open access
- closed
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