The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrocatalytic Performance of Fuel Oxidation by Pt3Ti Nanoparticles
Abstract
A Pt-based electrocatalyst for direct fuel cells, Pt3Ti, has been prepared in the form of nanoparticles. Pt(1,5-cyclooctadiene)Cl2 and Ti(tetrahydrofuran)2Cl4 are reduced by sodium naphthalide in tetrahydrofuran to form atomically disordered Pt3Ti nanoparticles (FCC-type structure: Fm3m; a = 0.39 nm; particle size = 3 +/- 0.4 nm). These atomically disordered Pt3Ti nanoparticles are transformed to larger atomically ordered Pt3Ti nanoparticles (Cu3Au-type structure: Pm3m; a = 0.3898 nm; particle size = 37 +/- 23 nm) by annealing above 400 degrees C. Both atomically disordered and ordered Pt3Ti nanoparticles show lower onset potentials for the oxidation of formic acid and methanol than either pure Pt or Pt-Ru nanoparticles. Both atomically disordered and ordered Pt3Ti nanoparticles show a much lower affinity for CO adsorption than either pure Pt or Pt-Ru nanoparticles. Atomically ordered Pt3Ti nanoparticles show higher oxidation current densities for both formic acid and methanol than pure Pt, Pt-Ru, or atomically disordered Pt3Ti nanoparticles. Pt3Ti nanoparticles, in particular the atomically ordered materials, have promise as anode catalysts for direct fuel cells.
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Citations
Cites
Electrocatalytic Activity of Ordered Intermetallic Phases for Fuel Cell Applications
Casado-Rivera, E., Volpe, D. J., Alden, L., Lind, C., Downie, C., Vázquez-Alvarez, T., Angelo, A. C. D., DiSalvo, F. J., & Abruña, H. D. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038497a · Cited by 521
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Cited by
Catalytic applications of layered double hydroxides: recent advances and perspectives
Fan, G., Li, F., Evans, D. G., & Duan, X. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00160e · Cited by 1,762
Sulfur-anchoring synthesis of platinum intermetallic nanoparticle catalysts for fuel cells
Yang, C.-L., Wang, L.-N., Yin, P., Liu, J., Chen, M.-X., Yan, Q.-Q., Wang, Z.-S., Xu, S.-L., Chu, S.-Q., Cui, C., et al. (2021) · Science · doi:10.1126/science.abj9980 · Cited by 908
Synthesis and Electrocatalytic Properties of Cubic Mn−Pt Nanocrystals (Nanocubes)
Kang, Y., & Murray, C. B. (2010) · Journal of the American Chemical Society · doi:10.1021/ja100705j · Cited by 352
Qi, Z., Xiao, C., Liu, C., Goh, T. W., Zhou, L., Maligal-Ganesh, R., Pei, Y., Li, X., Curtiss, L. A., & Huang, W. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12780 · Cited by 331
Li, Z., Qi, Z., Wang, S., Ma, T., Zhou, L., Wu, Z., Luan, X., Lin, F.-Y., Chen, M., Miller, J. T., et al. (2019) · Nano Letters · doi:10.1021/acs.nanolett.9b01381 · Cited by 210
Metadata
- Authors
- Abe, H., Matsumoto, F., Alden, L. R., Warren, S. C., Abruña, H. D., & DiSalvo, F. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-28
- Volume
- 130
- Issue
- 16
- Pages
- 5452-5458
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2023380363
- Cited by
- 170
- References
- 1
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
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