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Supramolecular Isomerism, Framework Flexibility, Unsaturated Metal Center, and Porous Property of Ag(I)/Cu(I) 3,3‘,5,5‘-Tetrametyl-4,4‘-Bipyrazolate
Abstract
Template-controlled reactions of 3,3',5,5'-tetramethyl-4,4'-bipyrazole (H2bpz) with [Ag(NH3)2]+ or [Cu(NH3)2]+ give binary metal bipyrazolates [M2(bpz)] (M = Ag, Cu) as two supramolecular isomers (1 and 2). Isomer 1 possesses four-fold interpenetrated (10,3)-a coordination networks, two-fold interpenetrated (10,3)-a channel networks, and guest-accessible coordinatively unsaturated metal clusters. Isomer 2 possesses eight-fold interpenetrated (6(2) x 10)(6 x 10(2)) coordination networks and isolated, small pores. These metal bipyrazolates are chemically stable and thermally stable up to 300-500 degrees C. Their exceptional framework flexibilities have been demonstrated by adsorption measurements and single-crystal diffraction analyses. The guest-accessible Ag(I)/Cu(I) UMC clusters have also been demonstrated to facilitate the accommodation of unsaturated hydrocarbons such as benzene, toluene, mesitylene, and acetylene via weak metal...pi interactions.
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Metadata
- Authors
- Zhang, J.-P., & Kitagawa, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-01-01
- Volume
- 130
- Issue
- 3
- Pages
- 907-917
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2070989955
- Cited by
- 346
- References
- 0
- FWCI
- 21.21
- Type
- journal article
- Language
- en
- Open access
- closed
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