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Copper-Catalyzed Arylation of Heterocycle C−H Bonds
Open accessAbstract
A new method for the direct, copper-catalyzed arylation of heterocycle C−H bonds by aryl halides has been developed. In addition to electron-rich five-membered heterocycles, electron-poor pyridine oxides can also be arylated. The best results are obtained by using a combination of lithium tert -butoxide base, aryl iodide coupling partner, and copper iodide catalyst.
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Citations
Cited by
3d Transition Metals for C–H Activation
Gandeepan, P., Müller, T., Zell, D., Cera, G., Warratz, S., & Ackermann, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00507 · Cited by 2,332
Copper‐Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights
Wendlandt, A. E., Suess, A. M., & Stahl, S. S. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103945 · Cited by 1,292
Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds
Do, H.-Q., & Daugulis, O. (2008) · Journal of the American Chemical Society · doi:10.1021/ja077862l · Cited by 454
Self-citationDirect Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates
Molander, G. A., Colombel, V., & Braz, V. A. (2011) · Organic Letters · doi:10.1021/ol2003572 · Cited by 288
Gupta, A., Jamatia, R., Patil, R. A., Ma, Y.-R., & Pal, A. K. (2018) · ACS Omega · doi:10.1021/acsomega.8b00334 · Cited by 106
Metadata
- Authors
- Do, H.-Q., & Daugulis, O.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-22
- Volume
- 129
- Issue
- 41
- Pages
- 12404-12405
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2028351186
- Cited by
- 524
- References
- 0
- FWCI
- 26.63
- Type
- journal article
- Language
- en
- Open access
- green
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