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Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials
Abstract
The synthesis and hydrogen uptake properties of metal−organic framework (MOFs) materials based on carboranes have been investigated. These are the first MOFs to make use of boron-rich components as building blocks specifically, the deprotonated form of 1,12-dihydroxycarbonyl-1,12-dicarba- closo -dodecaborane. In evacuated form the initially obtained compound, featuring zinc-coordinated solvent molecules, displays modest H 2 uptake at 77 K and 1 atm. Upon removal of the coordinated solvent, however, the uptake triples (2.1 wt. %), the heat of adsorption substantially increases, and the structure adjusts such that the pore size decreases.
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Cited by
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Dash, B. P., Satapathy, R., Gaillard, E. R., Maguire, J. A., & Hosmane, N. S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101845m · Cited by 272
Metadata
- Authors
- Farha, O. K., Spokoyny, A. M., Mulfort, K. L., Hawthorne, M. F., Mirkin, C. A., & Hupp, J. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-27
- Volume
- 129
- Issue
- 42
- Pages
- 12680-12681
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2021834633
- Cited by
- 289
- References
- 0
- FWCI
- 17.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Farha, O. K., Spokoyny, A. M., Mulfort, K. L., Hawthorne, M. F., Mirkin, C. A., & Hupp, J. T. (2007). Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials. Journal of the American Chemical Society. https://doi.org/10.1021/ja076167a
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