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High Mobility Single-Crystal Field-Effect Transistors from Bisindoloquinoline Semiconductors
Abstract
A novel heptacyclic bisindoloquinoline-based organic semiconductor has been synthesized, characterized, and used to fabricate single-crystal field-effect transistors. A synthetic route was developed for the synthesis of heptacyclic bis(indolo{1,2-a})quinoline via an intramolecular cyclization of anthrazoline derivatives. Single-crystal X-ray structure revealed that the seven fused rings of bis(indolo{1,2-a})quinoline are relatively coplanar and lead to a slipped face-to-face π-stacking with the shortest intermolecular spacing of 3.3 Å. Single-crystal field-effect transistors based on the bis(indolo{1,2-a})quinoline had carrier mobility as high as 1.0 cm 2 /V·s with on/off ratios greater than 10 4 .
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Electron Transport Materials for Organic Light-Emitting Diodes
Kulkarni, A. P., Tonzola, C. J., Babel, A., & Jenekhe, S. A. (2004) · Chemistry of Materials · doi:10.1021/cm049473l · Cited by 1,624
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Recent Advances in the Friedländer Reaction
Marco-Contelles, J., Pérez-Mayoral, E., Samadi, A., Carreiras, M. D. C., & Soriano, E. (2009) · Chemical Reviews · doi:10.1021/cr800482c · Cited by 666
Metadata
- Authors
- Ahmed, E., Briseno, A. L., Xia, Y., & Jenekhe, S. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-01-03
- Volume
- 130
- Issue
- 4
- Pages
- 1118-1119
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2091938890
- Cited by
- 177
- References
- 1
- FWCI
- 11.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ahmed, E., Briseno, A. L., Xia, Y., & Jenekhe, S. A. (2008). High Mobility Single-Crystal Field-Effect Transistors from Bisindoloquinoline Semiconductors. Journal of the American Chemical Society. https://doi.org/10.1021/ja077444g
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