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Moisture-Resistant and Superhydrophobic Metal−Organic Frameworks Obtained via Postsynthetic Modification
Open accessAbstract
Postsynthetic covalent modification of metal-organic frameworks (MOFs) with long alkyl substituents is shown to protect these materials against moisture. These MOFs, which normally display hydrophilic properties, are readily converted into hydrophobic or superhydrophobic materials. Overcoming the inherent sensitivity of MOFs to water represents a major step forward in their widespread use in technology applications.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Porous materials for carbon dioxide separations
Siegelman, R. L., Kim, E. J., & Long, J. R. (2021) · Nature Materials · doi:10.1038/s41563-021-01054-8 · Cited by 722
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Zhang, G., Wei, G., Liu, Z., Oliver, S. R. J., & Fei, H. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02511 · Cited by 217
Metadata
- Authors
- Nguyen, J. G., & Cohen, S. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-03-16
- Volume
- 132
- Issue
- 13
- Pages
- 4560-4561
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1983054423
- Cited by
- 571
- References
- 1
- FWCI
- 17.08
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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