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Cited by 238

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Imaging Structure Sensitive Catalysis on Different Shape-Controlled Platinum Nanoparticles

Sánchez-Sánchez, Carlos M., Solla-Gullón, José, Vidal-Iglesias, Francisco J., Aldaz, Antonio, Montiel, Vicente, Herrero, Enrique·2010·Journal of the American Chemical Society

Abstract

The structure sensitive catalytic activity for oxygen reduction reaction (ORR) on shape-controlled Pt nanoparticles (NPs) is directly imaged using scanning electrochemical microscopy (SECM). We synthesize and compare four types of Pt NPs: spherical, cubic, hexagonal, and tetrahedral-octahedral. Our SECM images show the hexagonal Pt NPs displaying the highest activity for ORR in two acid electrolytes. Meanwhile, cubic and tetrahedral-octahedral NPs drastically change their activity depending on specific adsorption of the different anions in solution. The NPs morphology produces predominant crystallographic planes at the surface of these shape-controlled Pt NPs, which are responsible for their different catalytic activity. Our results translate the studies on Pt single crystal electrodes present in the literature into Pt NPs that are useful as a catalyst in real fuel cells.

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Metadata

Authors
Sánchez-Sánchez, C. M., Solla-Gullón, J., Vidal-Iglesias, F. J., Aldaz, A., Montiel, V., & Herrero, E.
Venue
Journal of the American Chemical Society
Published
2010-04-01
Volume
132
Issue
16
Pages
5622-5624
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2022984826
Cited by
238
References
2
FWCI
11.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Imaging Structure Sensitive Catalysis on Different Shape-Controlled Platinum Nanoparticles. https://app.cochat.ai/papers/10.1021/ja100922h
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Sánchez-Sánchez, C. M., Solla-Gullón, J., Vidal-Iglesias, F. J., Aldaz, A., Montiel, V., & Herrero, E. (2010). Imaging Structure Sensitive Catalysis on Different Shape-Controlled Platinum Nanoparticles. Journal of the American Chemical Society. https://doi.org/10.1021/ja100922h

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