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A Thieno[3,4-c]pyrrole-4,6-dione-Based Copolymer for Efficient Solar Cells

Open access
Zou, Yingping, Najari, Ahmed, Berrouard, Philippe, Beaupré, Serge, Réda Aïch, Badrou, Tao, Ye, Leclerc, Mario·2010·Journal of the American Chemical Society

Abstract

A new low-band-gap thieno[3,4-c]pyrrole-4,6-dione-based copolymer, PBDTTPD, has been designed and synthesized. PBDTTPD is soluble in chloroform or o-dichlorobenzene upon heating and shows a broad absorption in the visible region. The HOMO and LUMO energy levels were estimated to be at -5.56 and -3.75 eV, respectively. These electrochemical measurements fit well with an optical bandgap of 1.8 eV. When blended with PC(71)BM, this polymer demonstrated a power conversion efficiency of 5.5% in a bulk-heterojunction photovoltaic device having an active area of 1.0 cm(2).

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Metadata

Authors
Zou, Y., Najari, A., Berrouard, P., Beaupré, S., Réda Aïch, B., Tao, Y., & Leclerc, M.
Venue
Journal of the American Chemical Society
Published
2010-03-29
Volume
132
Issue
15
Pages
5330-5331
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2018141019
Cited by
769
References
1
FWCI
96.19
Type
journal article
Language
en
Open access
green

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Zou, Y., Najari, A., Berrouard, P., Beaupré, S., Réda Aïch, B., Tao, Y., & Leclerc, M. (2010). A Thieno[3,4-c]pyrrole-4,6-dione-Based Copolymer for Efficient Solar Cells. Journal of the American Chemical Society. https://doi.org/10.1021/ja101888b

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