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Explanation of the Adsorption of Polar Vapors in the Highly Flexible Metal Organic Framework MIL-53(Cr)
Abstract
A comparison of the adsorption of water, methanol, and ethanol polar vapors by the flexible porous chromium(III) terephthalate MIL-53(Cr) was investigated by complementary techniques including adsorption gravimetry, ex situ X-ray powder diffraction, microcalorimetry, thermal analysis, IR spectroscopy, and molecular modeling. The breathing steps observed during adsorption strongly depend on the nature of the vapor. With water, a significant contraction of the framework is observed. For the alcohols, the initial contraction is followed by an expansion of the framework. A combination of IR analysis, X-ray diffraction, and computer modeling leads to the molecular localization of the guest molecules and to the identification of the specific guest-guest and host-guest interactions. The enthalpies of adsorption, measured by microcalorimetry, show that the strength of the interactions decreases from ethanol to water. Differential scanning calorimetry experiments on an EtOH/H(2)O mixture suggest a selective adsorption of ethanol over water.
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Cites
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Galizia, M., Chi, W. S., Smith, Z. P., Merkel, T. C., Baker, R. W., & Freeman, B. D. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01718 · Cited by 989
Li, L., Xiang, S., Cao, S., Zhang, J., Ouyang, G., Chen, L., & Su, C.-Y. (2013) · Nature Communications · doi:10.1038/ncomms2757 · Cited by 394
Solvothermal synthesis of NH2-MIL-125(Ti) from circular plate to octahedron
Hu, S., Liu, M., Li, K., Zuo, Y., Zhang, A., Song, C., Zhang, G., & Guo, X. (2014) · CrystEngComm · doi:10.1039/c4ce01545b · Cited by 269
CO 2 Adsorption in the RHO Family of Embedded Isoreticular Zeolites
Min, J. G., Kemp, K. C., Lee, H., & Hong, S. B. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b09996 · Cited by 53
Metadata
- Authors
- Bourrelly, S., Moulin, B., Rivera, A., Maurin, G., Devautour-Vinot, S., Serre, C., Devic, T., Horcajada, P., Vimont, A., Clet, G., Daturi, M., Lavalley, J.-C., Loera-Serna, S., Denoyel, R., Llewellyn, P. L., & Férey, G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-06-22
- Volume
- 132
- Issue
- 27
- Pages
- 9488-9498
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2045862747
- Cited by
- 215
- References
- 1
- FWCI
- 9.71
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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