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Total Structure Determination of Thiolate-Protected Au38 Nanoparticles
Abstract
We report the total structure of Au(38)(SC(2)H(4)Ph)(24) nanoparticles determined by single crystal X-ray crystallography. This nanoparticle is based upon a face-fused Au(23) biicosahedral core, which is further capped by three monomeric Au(SR)(2) staples at the waist of the Au(23) rod and six dimeric staples with three on the top icosahedron and other three on the bottom icosahedron. The six Au(2)(SR)(3) staples are arranged in a staggered configuration, and the Au(38)S(24) framework has a C(3) rotation axis.
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Cited by
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Chemical Flexibility of Atomically Precise Metal Clusters
Li, S., Li, N.-N., Dong, X.-Y., Zang, S.-Q., & Mak, T. C. W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00896 · Cited by 280
Transformation Chemistry of Gold Nanoclusters: From One Stable Size to Another
Zeng, C., Chen, Y., Das, A., & Jin, R. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01150 · Cited by 258
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Metadata
- Authors
- Qian, H., Eckenhoff, W. T., Zhu, Y., Pintauer, T., & Jin, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-06-01
- Volume
- 132
- Issue
- 24
- Pages
- 8280-8281
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2024854660
- Cited by
- 1,105
- References
- 0
- FWCI
- 34.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Qian, H., Eckenhoff, W. T., Zhu, Y., Pintauer, T., & Jin, R. (2010). Total Structure Determination of Thiolate-Protected Au38 Nanoparticles. Journal of the American Chemical Society. https://doi.org/10.1021/ja103592z
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