The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
Abstract
Reaction of AlCl(3)·6H(2)O with 2,2'-bipyridine-5,5'-dicarboxylic acid (H(2)bpydc) affords Al(OH)(bpydc) (1, MOF-253), the first metal-organic framework with open 2,2'-bipyridine (bpy) coordination sites. The material displays a BET surface area of 2160 m(2)/g and readily complexes metals to afford, for example, 1·xPdCl(2) (x = 0.08, 0.83) and 1·0.97Cu(BF(4))(2). EXAFS spectroscopy performed on 1·0.83PdCl(2) reveals the expected square planar coordination geometry, matching the structure of the model complex (bpy)PdCl(2). Significantly, the selectivity factor for binding CO(2) over N(2) under typical flue gas conditions is observed to increase from 2.8 in 1 to 12 in 1·0.97Cu(BF(4))(2).
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Self-citationMetal-organic frameworks with high capacity and selectivity for harmful gases
Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0804900105 · Cited by 958
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Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications
Gao, C., Low, J., Long, R., Kong, T., Zhu, J., & Xiong, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00840 · Cited by 1,050
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Younas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
Metal organic frameworks as precursors for the manufacture of advanced catalytic materials
Oar-Arteta, L., Wezendonk, T., Sun, X., Kapteijn, F., & Gascon, J. (2017) · Materials Chemistry Frontiers · doi:10.1039/c7qm00007c · Cited by 361
Metadata
- Authors
- Bloch, E. D., Britt, D., Lee, C., Doonan, C. J., Uribe-Romo, F. J., Furukawa, H., Long, J. R., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-17
- Volume
- 132
- Issue
- 41
- Pages
- 14382-14384
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2051191132
- Cited by
- 568
- References
- 3
- FWCI
- 23.88
- Type
- journal article
- Language
- en
- Open access
- closed
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