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Chromatography in a Single Metal−Organic Framework (MOF) Crystal
Abstract
Millimeter-sized single MOF-5 crystals are used as "chromatographic columns" to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Metal–Organic Frameworks for Food Safety
Wang, P.-L., Xie, L.-H., Joseph, E. A., Li, J.-R., Su, X.-O., & Zhou, H.-C. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00257 · Cited by 533
Metadata
- Authors
- Han, S., Wei, Y., Valente, C., Lagzi, I., Gassensmith, J. J., Coskun, A., Stoddart, J. F., & Grzybowski, B. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-01
- Volume
- 132
- Issue
- 46
- Pages
- 16358-16361
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2019903242
- Cited by
- 196
- References
- 0
- FWCI
- 14.56
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Chromatography in a Single Metal−Organic Framework (MOF) Crystal. https://app.cochat.ai/papers/10.1021/ja1074322
- The paper
- Han, S., Wei, Y., Valente, C., Lagzi, I., Gassensmith, J. J., Coskun, A., Stoddart, J. F., & Grzybowski, B. A. (2010). Chromatography in a Single Metal−Organic Framework (MOF) Crystal. Journal of the American Chemical Society. https://doi.org/10.1021/ja1074322
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
