The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Single-Molecule Magnet Behavior for an Antiferromagnetically Superexchange-Coupled Dinuclear Dysprosium(III) Complex
Abstract
A family of five dinuclear lanthanide complexes has been synthesized with general formula [Ln(III)(2)(valdien)(2)(NO(3))(2)] where (H(2)valdien = N1,N3-bis(3-methoxysalicylidene)diethylenetriamine) and Ln(III) = Eu(III)1, Gd(III)2, Tb(III)3, Dy(III)4, and Ho(III)5. The magnetic investigations reveal that 4 exhibits single-molecule magnet (SMM) behavior with an anisotropic barrier U(eff) = 76 K. The step-like features in the hysteresis loops observed for 4 reveal an antiferromagnetic exchange coupling between the two dysprosium ions. Ab initio calculations confirm the weak antiferromagnetic interaction with an exchange constant J(Dy-Dy) = -0.21 cm(-1). The observed steps in the hysteresis loops correspond to a weakly coupled system similar to exchange-biased SMMs. The Dy(2) complex is an ideal candidate for the elucidation of slow relaxation of the magnetization mechanism seen in lanthanide systems.
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Cites
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Taking advantage of luminescent lanthanide ions
Bünzli, J.-C. G., & Piguet, C. (2005) · Chemical Society Reviews · doi:10.1039/b406082m · Cited by 3,797
Lanthanide-Based Luminescent Hybrid Materials
Binnemans, K. (2009) · Chemical Reviews · doi:10.1021/cr8003983 · Cited by 3,349
Molecular spintronics using single-molecule magnets
Bogani, L., & Wernsdorfer, W. (2008) · Nature Materials · doi:10.1038/nmat2133 · Cited by 3,174
Self-citationHard and soft acids and bases, HSAB, part 1: Fundamental principles
Pearson, R. G. (1968) · Journal of Chemical Education · doi:10.1021/ed045p581 · Cited by 2,511
MOLCAS: a program package for computational chemistry
Karlström, G., Lindh, R., Malmqvist, P.-Å., Roos, B. O., Ryde, U., Veryazov, V., Widmark, P.-O., Cossi, M., Schimmelpfennig, B., Neogrady, P., et al. (2003) · Computational Materials Science · doi:10.1016/s0927-0256(03)00109-5 · Cited by 1,748
Magnetism of Lanthanides in Molecular Materials with Transition-Metal Ions and Organic Radicals
Benelli, C., & Gatteschi, D. (2002) · Chemical Reviews · doi:10.1021/cr010303r · Cited by 1,600
Aquilante, F., De Vico, L., Ferré, N., Ghigo, G., Malmqvist, P., Neogrády, P., Pedersen, T. B., Pitoňák, M., Reiher, M., Roos, B. O., et al. (2010) · Journal of Computational Chemistry · doi:10.1002/jcc.21318 · Cited by 1,554
The Rich Stereochemistry of Eight‐Vertex Polyhedra: A Continuous Shape Measures Study
Casanova, D., Llunell, M., Alemany, P., & Álvarez, S. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200400799 · Cited by 991
Paramagnetic Relaxation Times for Titanium and Chrome Alum
Van Vleck, J. H. (1940) · Physical Review · doi:10.1103/physrev.57.426 · Cited by 877
Coronado, E., & Day, P. (2004) · Chemical Reviews · doi:10.1021/cr030641n · Cited by 861
Spin-lattice relaxation in rare-earth salts
Orbach, R. :. (1961) · Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences · doi:10.1098/rspa.1961.0211 · Cited by 847
Parker, D., Dickins, R. S., Puschmann, H., Crossland, C., & Howard, J. A. K. (2002) · Chemical Reviews · doi:10.1021/cr010452+ · Cited by 834
Lanthanide Complexes in Molecular Recognition and Chirality Sensing of Biological Substrates
Tsukube, H., & Shinoda, S. (2002) · Chemical Reviews · doi:10.1021/cr010450p · Cited by 631
Reduced Anionic Mn12Molecules with Half-Integer Ground States as Single-Molecule Magnets
Aubin, S. M. J., Sun, Z., Pardi, L., Krzystek, J., Folting, K., Brunel, L.-C., Rheingold, A. L., Christou, G., & Hendrickson, D. N. (1999) · Inorganic Chemistry · doi:10.1021/ic990613g · Cited by 620
Chibotaru, L. F., Ungur, L., Aronica, C., Moll, H. E., Pilet, G., & Luneau, D. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8029416 · Cited by 534
Self-citationAronica, C., Pilet, G., Chastanet, G., Wernsdorfer, W., Jacquot, J., & Luneau, D. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200600513 · Cited by 319
Self-citationA promising new route towards single-molecule magnets based on the oxalate ligand
Xu, G.-F., Wang, Q.-L., Gamez, P., Ma, Y., Clérac, R., Tang, J., Yan, S.-P., Cheng, P., & Liao, D.-Z. (2010) · Chem. Commun. · doi:10.1039/b920215c · Cited by 240
Advances in acyclic compartmental ligands and related complexes
Vigato, P. A., & Tamburini, S. (2008) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2007.10.030 · Cited by 181
Chakov, N. E., Lee, S.-C., Harter, A. G., Kuhns, P. L., Reyes, A. P., Hill, S. O., Dalal, N. S., Wernsdorfer, W., Abboud, K. A., & Christou, G. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060796n · Cited by 164
Self-citationMagnetic Coupling in Dinuclear Gd Complexes
Roy, L. E., & Hughbanks, T. (2006) · Journal of the American Chemical Society · doi:10.1021/ja055035j · Cited by 161
Gu, X., & Xue, D. (2007) · Inorganic Chemistry · doi:10.1021/ic0623056 · Cited by 123
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Woodruff, D. N., Winpenny, R. E. P., & Layfield, R. A. (2013) · Chemical Reviews · doi:10.1021/cr400018q · Cited by 2,781
Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
Zabala-Lekuona, A., Seco, J. M., & Colacio, E. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213984 · Cited by 459
Metadata
- Authors
- Long, J., Habib, F., Lin, P.-H., Korobkov, I., Enright, G., Ungur, L., Wernsdorfer, W., Chibotaru, L. F., & Murugesu, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-22
- Volume
- 133
- Issue
- 14
- Pages
- 5319-5328
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318964624
- Cited by
- 594
- References
- 23
- FWCI
- 21.45
- Type
- journal article
- Language
- en
- Open access
- closed
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