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Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers
Abstract
Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science.
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Cited by
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Blasco, E., Sims, M. B., Goldmann, A. S., Sumerlin, B. S., & Barner-Kowollik, C. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b00465 · Cited by 437
Tian, T., Hu, R., & Tang, B. Z. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02886 · Cited by 294
From Polyethylene to Polyester: Influence of Ester Groups on the Physical Properties
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Metadata
- Authors
- Kreye, O., Tóth, T., & Meier, M. A. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-01-25
- Volume
- 133
- Issue
- 6
- Pages
- 1790-1792
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1992167318
- Cited by
- 375
- References
- 0
- FWCI
- 8.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kreye, O., Tóth, T., & Meier, M. A. R. (2011). Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers. Journal of the American Chemical Society. https://doi.org/10.1021/ja1113003
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