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Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers

Kreye, Oliver, Tóth, Tommy, Meier, Michael A. R.·2011·Journal of the American Chemical Society

Abstract

Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science.

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Metadata

Authors
Kreye, O., Tóth, T., & Meier, M. A. R.
Venue
Journal of the American Chemical Society
Published
2011-01-25
Volume
133
Issue
6
Pages
1790-1792
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1992167318
Cited by
375
References
0
FWCI
8.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers. https://app.cochat.ai/papers/10.1021/ja1113003
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Kreye, O., Tóth, T., & Meier, M. A. R. (2011). Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers. Journal of the American Chemical Society. https://doi.org/10.1021/ja1113003

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.