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Cited by 728

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Metal-free Inorganic Ligands for Colloidal Nanocrystals: S2–, HS–, Se2–, HSe–, Te2–, HTe–, TeS32–, OH–, and NH2– as Surface Ligands

Nag, Angshuman, Kovalenko, Maksym V., Lee, Jong-Soo, Liu, Wenyong, Spokoyny, Boris, Talapin, Dmitri V.·2011·Journal of the American Chemical Society

Abstract

All-inorganic colloidal nanocrystals were synthesized by replacing organic capping ligands on chemically synthesized nanocrystals with metal-free inorganic ions such as S(2-), HS(-), Se(2-), HSe(-), Te(2-), HTe(-), TeS(3)(2-), OH(-) and NH(2)(-). These simple ligands adhered to the NC surface and provided colloidal stability in polar solvents. The versatility of such ligand exchange has been demonstrated for various semiconductor and metal nanocrystals of different size and shape. We showed that the key aspects of Pearson's hard and soft acids and bases (HSAB) principle, originally developed for metal coordination compounds, can be applied to the bonding of molecular species to the nanocrystal surface. The use of small inorganic ligands instead of traditional ligands with long hydrocarbon tails facilitated the charge transport between individual nanocrystals and opened up interesting opportunities for device integration of colloidal nanostructures.

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Metadata

Authors
Nag, A., Kovalenko, M. V., Lee, J.-S., Liu, W., Spokoyny, B., & Talapin, D. V.
Venue
Journal of the American Chemical Society
Published
2011-06-17
Volume
133
Issue
27
Pages
10612-10620
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2033982667
Cited by
728
References
1
FWCI
27.11
Type
journal article
Language
en
Open access
closed

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