The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Redox Control of a Ring-Opening Polymerization Catalyst
Abstract
The activity of an yttrium alkoxide complex supported by a ferrocene-based ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The oxidized complex was characterized by X-ray crystallography and (1)H NMR, XANES, and Mössbauer spectroscopy. Switching in situ between the oxidized and reduced yttrium complexes resulted in a change in the rate of polymerization of L-lactide. Synthesized polymers were analyzed by gel permeation chromatography. Polymerization of trimethylene carbonate was also performed with the reduced and oxidized forms of an indium alkoxide complex. The indium system showed the opposite behavior to that of yttrium, revealing a metal-based dependency on the rate of polymerization.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Bouyahyi, M., Ajellal, N., Kirillov, E., Thomas, C. M., & Carpentier, J. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201002779 · Cited by 217
Cited by
Wang, X., Thevenon, A., Brosmer, J. L., Yu, I., Khan, S. I., Mehrkhodavandi, P., & Diaconescu, P. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505883u · Cited by 263
Self-citationGuillaume, S. M., Kirillov, E., Sarazin, Y., & Carpentier, J. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201500613 · Cited by 251
Bakewell, C., Cao, T.-P.-A., Long, N., Le Goff, X. F., Auffrant, A., & Williams, C. K. (2012) · Journal of the American Chemical Society · doi:10.1021/ja310003v · Cited by 226
Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates
Dagorne, S., Normand, M., Kirillov, E., & Carpentier, J.-F. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.02.012 · Cited by 215
Biernesser, A. B., Delle Chiaie, K. R., Curley, J. B., & Byers, J. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201511793 · Cited by 165
Metadata
- Authors
- Broderick, E. M., Guo, N., Vogel, C. S., Xu, C., Sutter, J., Miller, J. T., Meyer, K., Mehrkhodavandi, P., & Diaconescu, P. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-05-25
- Volume
- 133
- Issue
- 24
- Pages
- 9278-9281
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313933466
- Cited by
- 254
- References
- 2
- FWCI
- 6.42
- Type
- journal article
- Language
- en
- Open access
- closed
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