The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
Abstract
The efficient capture and storage of gaseous CO(2) is a pressing environmental problem. Although porous metal-organic frameworks (MOFs) have been shown to be very effective at adsorbing CO(2) selectively by dint of dipole-quadruple interactions and/or ligation to open metal sites, the gas is not usually trapped covalently. Furthermore, the vast majority of these MOFs are fabricated from nonrenewable materials, often in the presence of harmful solvents, most of which are derived from petrochemical sources. Herein we report the highly selective adsorption of CO(2) by CD-MOF-2, a recently described green MOF consisting of the renewable cyclic oligosaccharide γ-cyclodextrin and RbOH, by what is believed to be reversible carbon fixation involving carbonate formation and decomposition at room temperature. The process was monitored by solid-state (13)C NMR spectroscopy as well as colorimetrically after a pH indicator was incorporated into CD-MOF-2 to signal the formation of carbonic acid functions within the nanoporous extended framework.
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Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Self-citationAdsorbents: Fundamentals and Applications
Yang, R. T. (2003) · doi:10.1002/047144409x · Cited by 1,182
Kwak, J. H., Hu, J. Z., Hoyt, D. W., Sears, J. A., Wang, C., Rosso, K. M., & Felmy, A. R. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1001308 · Cited by 105
Cited by
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Self-citationRecycling of carbon dioxide to methanol and derived products – closing the loop
Goeppert, A., Czaun, M., Jones, J.-P., Surya Prakash, G. K., & Olah, G. A. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00122b · Cited by 1,528
Air as the renewable carbon source of the future: an overview of CO2 capture from the atmosphere
Goeppert, A., Czaun, M., Surya Prakash, G. K., & Olah, G. A. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21586a · Cited by 724
Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Hedin, N., Andersson, L., Bergström, L., & Yan, J. (2013) · Applied Energy · doi:10.1016/j.apenergy.2012.11.034 · Cited by 424
Metadata
- Authors
- Gassensmith, J. J., Furukawa, H., Smaldone, R. A., Forgan, R. S., Botros, Y. Y., Yaghi, O. M., & Stoddart, J. F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-09-13
- Volume
- 133
- Issue
- 39
- Pages
- 15312-15315
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974058936
- Cited by
- 392
- References
- 3
- FWCI
- 18.52
- Type
- journal article
- Language
- en
- Open access
- closed
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