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p-Xylene-Selective Metal–Organic Frameworks: A Case of Topology-Directed Selectivity
Open accessAbstract
Para-disubstituted alkylaromatics such as p-xylene are preferentially adsorbed from an isomer mixture on three isostructural metal-organic frameworks: MIL-125(Ti) ([Ti(8)O(8)(OH)(4)(BDC)(6)]), MIL-125(Ti)-NH(2) ([Ti(8)O(8)(OH)(4)(BDC-NH(2))(6)]), and CAU-1(Al)-NH(2) ([Al(8)(OH)(4)(OCH(3))(8)(BDC-NH(2))(6)]) (BDC = 1,4-benzenedicarboxylate). Their unique structure contains octahedral cages, which can separate molecules on the basis of differences in packing and interaction with the pore walls, as well as smaller tetrahedral cages, which are capable of separating molecules by molecular sieving. These experimental data are in line with predictions by molecular simulations. Additional adsorption and microcalorimetric experiments provide insight in the complementary role of the two cage types in providing the para selectivity.
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Cited by
Adsorptive separation on metal–organic frameworks in the liquid phase
Van de Voorde, B., Bueken, B., Denayer, J., & De Vos, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00006d · Cited by 874
Self-citationHe, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
Adsorption/catalytic properties of MIL-125 and NH2-MIL-125
Kim, S.-N., Kim, J., Kim, H.-Y., Cho, H.-Y., & Ahn, W.-S. (2013) · Catalysis Today · doi:10.1016/j.cattod.2012.08.014 · Cited by 528
Zhu, X., Li, B., Yang, J., Li, Y., Zhao, W., Shi, J., & Gu, J. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am5059074 · Cited by 486
Discrimination of xylene isomers in a stacked coordination polymer
Li, L., Guo, L., Olson, D. H., Xian, S., Zhang, Z., Yang, Q., Wu, K., Yang, Y., Bao, Z., Ren, Q., et al. (2022) · Science · doi:10.1126/science.abj7659 · Cited by 280
Metadata
- Authors
- Vermoortele, F., Maes, M., Moghadam, P. Z., Lennox, M. J., Ragon, F., Boulhout, M., Biswas, S., Laurier, K. G. M., Beurroies, I., Denoyel, R., Roeffaers, M., Stock, N., Düren, T., Serre, C., & De Vos, D. E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-10-27
- Volume
- 133
- Issue
- 46
- Pages
- 18526-18529
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2004610609
- Cited by
- 189
- References
- 0
- FWCI
- 10.03
- Type
- journal article
- Language
- en
- Open access
- green
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- Vermoortele, F., Maes, M., Moghadam, P. Z., Lennox, M. J., Ragon, F., Boulhout, M., Biswas, S., Laurier, K. G. M., Beurroies, I., Denoyel, R., Roeffaers, M., Stock, N., Düren, T., Serre, C., & De Vos, D. E. (2011). p-Xylene-Selective Metal–Organic Frameworks: A Case of Topology-Directed Selectivity. Journal of the American Chemical Society. https://doi.org/10.1021/ja207287h
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