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Cited by 182

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake

Lin, Qipu, Wu, Tao, Zheng, Shou-Tian, Bu, Xianhui, Feng, Pingyun·2012·Journal of the American Chemical Society

Abstract

The self-assembly between zinc dimer and 1,3,5-tris(2H-tetrazol-5-yl)benzene (H(3)BTT), promoted by a urea derivative, leads to a highly porous 3D framework with a large percentage (67%) of N-donor sites unused for bonding with metals. The material exhibits high gas storage capacity (ca. 1.89 wt % H(2) at 77 K and 1 atm; 98 cm(3)/g CO(2) at 273 K and 1 atm), even in the absence of open metal sites. The high percentage of open N-donor sites, coupled with the low framework density resulting from single-walled channels, is believed to contribute to the high uptake capacity.

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Metadata

Authors
Lin, Q., Wu, T., Zheng, S.-T., Bu, X., & Feng, P.
Venue
Journal of the American Chemical Society
Published
2011-12-19
Volume
134
Issue
2
Pages
784-787
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2313915764
Cited by
182
References
1
FWCI
14.85
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake. https://app.cochat.ai/papers/10.1021/ja2092882
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Lin, Q., Wu, T., Zheng, S.-T., Bu, X., & Feng, P. (2012). Single-Walled Polytetrazolate Metal–Organic Channels with High Density of Open Nitrogen-Donor Sites and Gas Uptake. Journal of the American Chemical Society. https://doi.org/10.1021/ja2092882

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