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Cited by 837

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Economical Pt-Free Catalysts for Counter Electrodes of Dye-Sensitized Solar Cells

Open access
Wu, Mingxing, Lin, Xiao, Wang, Yudi, Wang, Liang, Guo, Wei, Qi, Daidi, Peng, Xiaojun, Hagfeldt, Anders, Grätzel, Michael, Ma, Tingli·2012·Journal of the American Chemical Society

Abstract

Three classes (carbides, nitrides and oxides) of nanoscaled early-transition-metal catalysts have been proposed to replace the expensive Pt catalyst as counter electrodes (CEs) in dye-sensitized solar cells (DSCs). Of these catalysts, Cr(3)C(2), CrN, VC(N), VN, TiC, TiC(N), TiN, and V(2)O(3) all showed excellent catalytic activity for the reduction of I(3)(-) to I(-) in the electrolyte. Further, VC embedded in mesoporous carbon (VC-MC) was prepared through in situ synthesis. The I(3)(-)/I(-) DSC based on the VC-MC CE reached a high power conversion efficiency (PCE) of 7.63%, comparable to the photovoltaic performance of the DSC using a Pt CE (7.50%). In addition, the carbide catalysts demonstrated catalytic activity higher than that of Pt for the regeneration of a new organic redox couple of T(2)/T(-). The T(2)/T(-) DSCs using TiC and VC-MC CEs showed PCEs of 4.96 and 5.15%, much higher than that of the DSC using a Pt CE (3.66%). This work expands the list of potential CE catalysts, which can help reduce the cost of DSCs and thereby encourage their fundamental research and commercial application.

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Metadata

Authors
Wu, M., Lin, X., Wang, Y., Wang, L., Guo, W., Qi, D., Peng, X., Hagfeldt, A., Grätzel, M., & Ma, T.
Venue
Journal of the American Chemical Society
Published
2012-02-08
Volume
134
Issue
7
Pages
3419-3428
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2003682905
Cited by
837
References
1
FWCI
38.99
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Economical Pt-Free Catalysts for Counter Electrodes of Dye-Sensitized Solar Cells. https://app.cochat.ai/papers/10.1021/ja209657v
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Wu, M., Lin, X., Wang, Y., Wang, L., Guo, W., Qi, D., Peng, X., Hagfeldt, A., Grätzel, M., & Ma, T. (2012). Economical Pt-Free Catalysts for Counter Electrodes of Dye-Sensitized Solar Cells. Journal of the American Chemical Society. https://doi.org/10.1021/ja209657v

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