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F-Doped Co3O4 Photocatalysts for Sustainable H2 Generation from Water/Ethanol
Abstract
p-Type Co(3)O(4) nanostructured films are synthesized by a plasma-assisted process and tested in the photocatalytic production of H(2) from water/ethanol solutions under both near-UV and solar irradiation. It is demonstrated that the introduction of fluorine into p-type Co(3)O(4) results in a remarkable performance improvement with respect to the corresponding undoped oxide, highlighting F-doped Co(3)O(4) films as highly promising systems for hydrogen generation. Notably, the obtained yields were among the best ever reported for similar semiconductor-based photocatalytic processes.
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Cites
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Cited by
Defect engineering in photocatalytic materials
Bai, S., Zhang, N., Gao, C., & Xiong, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.08.058 · Cited by 1,236
Hydrogen from photo-catalytic water splitting process: A review
Ahmad, H., Kamarudin, S. K., Minggu, L. J., & Kassim, M. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.10.101 · Cited by 911
Metal-free photocatalysts for hydrogen evolution
Rahman, M. Z., Kibria, M. G., & Mullins, C. B. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00313d · Cited by 565
Photocatalytic production of hydrogen from biomass-derived feedstocks
Puga, A. V. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.12.009 · Cited by 440
Shen, L., Luo, M., Liu, Y., Liang, R., Jing, F., & Wu, L. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.11.056 · Cited by 358
Metadata
- Authors
- Gasparotto, A., Barreca, D., Bekermann, D., Devi, A., Fischer, R. A., Fornasiero, P., Gombac, V., Lebedev, O. I., Maccato, C., Montini, T., Van Tendeloo, G., & Tondello, E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-10
- Volume
- 133
- Issue
- 48
- Pages
- 19362-19365
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313406594
- Cited by
- 190
- References
- 2
- FWCI
- 5.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gasparotto, A., Barreca, D., Bekermann, D., Devi, A., Fischer, R. A., Fornasiero, P., Gombac, V., Lebedev, O. I., Maccato, C., Montini, T., Van Tendeloo, G., & Tondello, E. (2011). F-Doped Co3O4 Photocatalysts for Sustainable H2 Generation from Water/Ethanol. Journal of the American Chemical Society. https://doi.org/10.1021/ja210078d
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