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Cited by 618

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Enhancing Visible Light Photo-oxidation of Water with TiO2 Nanowire Arrays via Cotreatment with H2 and NH3: Synergistic Effects between Ti3+ and N

Hoang, Son, Berglund, Sean P., Hahn, Nathan T., Bard, Allen J., Mullins, C. Buddie·2012·Journal of the American Chemical Society

Abstract

We report a synergistic effect involving hydrogenation and nitridation cotreatment of TiO(2) nanowire (NW) arrays that improves the water photo-oxidation performance under visible light illumination. The visible light (>420 nm) photocurrent of the cotreated TiO(2) is 0.16 mA/cm(2) and accounts for 41% of the total photocurrent under simulated AM 1.5 G illumination. Electron paramagnetic resonance (EPR) spectroscopy reveals that the concentration of Ti(3+) species in the bulk of the TiO(2) following hydrogenation and nitridation cotreatment is significantly higher than that of the sample treated solely with ammonia. It is believed that the interaction between the N-dopant and Ti(3+) is the key to the extension of the active spectrum and the superior visible light water photo-oxidation activity of the hydrogenation and nitridation cotreated TiO(2) NW arrays.

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Metadata

Authors
Hoang, S., Berglund, S. P., Hahn, N. T., Bard, A. J., & Mullins, C. B.
Venue
Journal of the American Chemical Society
Published
2012-02-14
Volume
134
Issue
8
Pages
3659-3662
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2039010009
Cited by
618
References
3
FWCI
26.00
Type
journal article
Language
en
Open access
closed

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