The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
In Situ Growth of Metal Particles on 3D Urchin-like WO3 Nanostructures
Abstract
Metal/semiconductor hybrid materials of various sizes and morphologies have many applications in areas such as catalysis and sensing. Various organic agents are necessary to stabilize metal nanoparticles during synthesis, which leads to a layer of organic compounds present at the interfaces between the metal particles and the semiconductor supports. Generally, high-temperature oxidative treatment is used to remove the organics, which can extensively change the size and morphology of the particles, in turn altering their activity. Here we report a facile method for direct growth of noble-metal particles on WO(3) through an in situ redox reaction between weakly reductive WO(2.72) and oxidative metal salts in aqueous solution. This synthetic strategy has the advantages that it takes place in one step and requires no foreign reducing agents, stabilizing agents, or pretreatment of the precursors, making it a practical method for the controlled synthesis of metal/semiconductor hybrid nanomaterials. This synthetic method may open up a new way to develop metal-nanoparticle-loaded semiconductor composites.
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Cites
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
Cited by
Chen, D., Chen, C., Baiyee, Z. M., Shao, Z., & Ciucci, F. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00073 · Cited by 936
Tungsten Oxides for Photocatalysis, Electrochemistry, and Phototherapy
Huang, Z., Song, J., Pan, L., Zhang, X., Wang, L., & Zou, J. (2015) · Advanced Materials · doi:10.1002/adma.201501217 · Cited by 608
Hierarchical Nanostructures: Design for Sustainable Water Splitting
Fang, M., Dong, G., Wei, R., & Ho, J. C. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700559 · Cited by 357
Dai, K., Lu, L., Liang, C., Liu, Q., & Zhu, G. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.03.039 · Cited by 338
A metallic molybdenum dioxide with high stability for surface enhanced Raman spectroscopy
Zhang, Q., Li, X., Ma, Q., Zhang, Q., Bai, H., Yi, W., Liu, J., Han, J., & Xi, G. (2017) · Nature Communications · doi:10.1038/ncomms14903 · Cited by 323
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Metadata
- Authors
- Xi, G., Ye, J., Ma, Q., Su, N., Bai, H., & Wang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-04
- Volume
- 134
- Issue
- 15
- Pages
- 6508-6511
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313904556
- Cited by
- 356
- References
- 1
- FWCI
- 25.40
- Type
- journal article
- Language
- en
- Open access
- closed
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