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Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts
Abstract
Visible light along with 1 mol % eosin Y catalyzes the direct C-H bond arylation of heteroarenes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction for several aryl diazonium salts and heteroarenes. The general and easy procedure provides a transition-metal-free alternative for the formation of aryl-heteroaryl bonds.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
Shu, X.-Z., Zhang, M., He, Y., Frei, H., & Toste, F. D. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500716j · Cited by 435
Douglas, J. J., Sevrin, M. J., & Stephenson, C. R. J. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00125 · Cited by 361
Metadata
- Authors
- Hari, D. P., Schroll, P., & König, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-03
- Volume
- 134
- Issue
- 6
- Pages
- 2958-2961
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2081910612
- Cited by
- 798
- References
- 0
- FWCI
- 31.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts. https://app.cochat.ai/papers/10.1021/ja212099r
- The paper
- Hari, D. P., Schroll, P., & König, B. (2012). Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts. Journal of the American Chemical Society. https://doi.org/10.1021/ja212099r
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
