The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
ZSM-5 Zeolite Single Crystals with b-Axis-Aligned Mesoporous Channels as an Efficient Catalyst for Conversion of Bulky Organic Molecules
Abstract
The relatively small and sole micropores in zeolite catalysts strongly influence the mass transfer and catalytic conversion of bulky molecules. We report here aluminosilicate zeolite ZSM-5 single crystals with b-axis-aligned mesopores, synthesized using a designed cationicamphiphilic copolymer as a mesoscale template. This sample exhibits excellent hydrothermal stability. The orientation of the mesopores was confirmed by scanning and transmission electron microscopy. More importantly, the b-axis-aligned mesoporous ZSM-5 shows much higher catalytic activities for bulky substrate conversion than conventional ZSM-5 and ZSM-5 with randomly oriented mesopores. The combination of good hydrothermal stability with high activities is important for design of novel zeolite catalysts. The b-axis-aligned mesoporous ZSM-5 reported here shows great potential for industrial applications.
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Cites
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Deng, Y., Yu, T., Wan, Y., Shi, Y., Meng, Y., Gu, D., Zhang, L., Huang, Y., Liu, C., Wu, X., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067379v · Cited by 402
Cited by
Sun, M.-H., Huang, S.-Z., Chen, L.-H., Li, Y., Yang, X.-Y., Yuan, Z.-Y., & Su, B.-L. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00135a · Cited by 1,454
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Design and fabrication of mesoporous heterogeneous basic catalysts
Sun, L.-B., Liu, X.-Q., & Zhou, H.-C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00090d · Cited by 386
From 3D to 2D zeolite catalytic materials
Přech, J., Pizarro, P., Serrano, D. P., & Čejka, J. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00370j · Cited by 313
Zhu, J., Zhu, Y., Zhu, L., Rigutto, M., van der Made, A., Yang, C., Pan, S., Wang, L., Zhu, L., Jin, Y., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411117y · Cited by 305
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Metadata
- Authors
- Liu, F., Willhammar, T., Wang, L., Zhu, L., Sun, Q., Meng, X., Carrillo-Cabrera, W., Zou, X., & Xiao, F.-S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-05
- Volume
- 134
- Issue
- 10
- Pages
- 4557-4560
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1980515740
- Cited by
- 288
- References
- 2
- FWCI
- 17.31
- Type
- journal article
- Language
- en
- Open access
- closed
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