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Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I
Open accessAbstract
This communication describes the development of a mild method for the cross-coupling of arylboronic acids with CF(3)I via the merger of photoredox and Cu catalysis. This method has been applied to the trifluoromethylation of electronically diverse aromatic and heteroaromatic substrates and tolerates many common functional groups.
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Citations
Cited by
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Noble, A., McCarver, S. J., & MacMillan, D. W. C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511913h · Cited by 448
Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
Shu, X.-Z., Zhang, M., He, Y., Frei, H., & Toste, F. D. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500716j · Cited by 435
Tang, X.-J., Thomoson, C. S., & Dolbier, W. R. (2014) · Organic Letters · doi:10.1021/ol502163f · Cited by 323
Recent advances in photoinduced trifluoromethylation and difluoroalkylation
Pan, X., Xia, H., & Wu, J. (2016) · Organic Chemistry Frontiers · doi:10.1039/c6qo00153j · Cited by 283
Metadata
- Authors
- Ye, Y., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-24
- Volume
- 134
- Issue
- 22
- Pages
- 9034-9037
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2016811654
- Cited by
- 682
- References
- 0
- FWCI
- 42.43
- Type
- journal article
- Language
- en
- Open access
- green
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- Ye, Y., & Sanford, M. S. (2012). Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I. Journal of the American Chemical Society. https://doi.org/10.1021/ja301553c
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
