The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
Abstract
We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal-organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to date (~7000 m(2)/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, is the use of a supercritical CO(2) activation technique. Additionally, we demonstrate computationally that by shifting from phenyl groups to "space efficient" acetylene moieties as linker expansion units, the hypothetical maximum surface area for a MOF material is substantially greater than previously envisioned (~14600 m(2)/g (or greater) versus ~10500 m(2)/g).
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationHorike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Cited by
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A. J., Luebke, R., Forrest, K., Pham, T., Ma, S., Space, B., Wojtas, L., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,387
Conductive MOF electrodes for stable supercapacitors with high areal capacitance
Sheberla, D., Bachman, J. C., Elias, J. S., Sun, C.-J., Shao-Horn, Y., & Dincă, M. (2017) · Nature Materials · doi:10.1038/nmat4766 · Cited by 2,370
Moghadam, P. Z., Li, A., Wiggin, S. B., Tao, A., Maloney, A. G. P., Wood, P. A., Ward, S. C., & Fairen-Jimenez, D. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b00441 · Cited by 1,082
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
Peng, Y., Krungleviciute, V., Eryazici, I., Hupp, J. T., Farha, O. K., & Yildirim, T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4045289 · Cited by 1,018
Self-citationMetal–organic frameworks for heavy metal removal from water
Kobielska, P. A., Howarth, A. J., Farha, O. K., & Nayak, S. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.12.010 · Cited by 1,014
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Metadata
- Authors
- Farha, O. K., Eryazici, I., Jeong, N. C., Hauser, B. G., Wilmer, C. E., Sarjeant, A. A., Snurr, R. Q., Nguyen, S. T., Yazaydın, A. Ö., & Hupp, J. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-31
- Volume
- 134
- Issue
- 36
- Pages
- 15016-15021
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2051808592
- Cited by
- 1,958
- References
- 2
- FWCI
- 51.40
- Type
- journal article
- Language
- en
- Open access
- closed
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