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Multipoint Interactions Enhanced CO2 Uptake: A Zeolite-like Zinc–Tetrazole Framework with 24-Nuclear Zinc Cages
Abstract
A zeolite-like microporous tetrazole-based metal-organic framework (MOF) with 24 nuclear zinc cages was synthesized and characterized. It exhibits high CO(2) adsorption capacity up to 35.6 wt % (8.09 mmol/g) and excellent CO(2)/CH(4) selectivity at 273 K/1 bar, being among the highest values known to date. Theoretical calculations based on simulated annealing techniques and periodic DFT revealed that CO(2) is predominantly located around the inner surface of the cages through multipoint interactions, in particular, around the aromatic tetrazole rings. Importantly, it is the first time that multipoint interactions between CO(2) molecules and frameworks resulting in high CO(2) uptake are observed.
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Cited by
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
Trickett, C. A., Helal, A., Al-Maythalony, B. A., Yamani, Z. H., Cordova, K. E., & Yaghi, O. M. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.45 · Cited by 1,524
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Self-citationMetal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
Lin, Z.-J., Lü, J., Hong, M., & Cao, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60483g · Cited by 874
Zhao, X., Bu, X., Zhai, Q.-G., Tran, H., & Feng, P. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512137t · Cited by 355
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Metadata
- Authors
- Cui, P., Ma, Y.-G., Li, H.-H., Zhao, B., Li, J.-R., Cheng, P., Balbuena, P. B., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-07
- Volume
- 134
- Issue
- 46
- Pages
- 18892-18895
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1965944206
- Cited by
- 242
- References
- 0
- FWCI
- 16.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Cui, P., Ma, Y.-G., Li, H.-H., Zhao, B., Li, J.-R., Cheng, P., Balbuena, P. B., & Zhou, H.-C. (2012). Multipoint Interactions Enhanced CO2 Uptake: A Zeolite-like Zinc–Tetrazole Framework with 24-Nuclear Zinc Cages. Journal of the American Chemical Society. https://doi.org/10.1021/ja3063138
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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