The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
The Nature of Lithium Battery Materials under Oxygen Evolution Reaction Conditions
Abstract
Transition-metal oxide and phosphate materials, commonly used for lithium battery devices, are active as oxygen evolution reaction (OER) catalysts under alkaline and neutral solution conditions. Electrodes composed of LiCoO(2) and LiCoPO(4) exhibit progressive deactivation and activation for OER catalysis, respectively, upon potential cycling at neutral pH. The deactivation of LiCoO(2) and activation of LiCoPO(4) are coincident with changes in surface morphology and composition giving rise to spinel-like and amorphous surface structures, respectively. The amorphous surface structure of the activated LiCoPO(4) is compositionally similar to that obtained from the electrodeposition of cobalt oxide materials from phosphate-buffered electrolyte solutions. These results highlight the importance of a combined structural and electrochemical analysis of the materials surface when assessing the true nature of the OER catalyst.
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Cites
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Self-citationProton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Chang, C. J., Chang, M. C. Y., Damrauer, N. H., & Nocera, D. G. (2004) · Biochimica et Biophysica Acta (BBA) - Bioenergetics · doi:10.1016/j.bbabio.2003.08.010 · Cited by 189
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Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting
Friebel, D., Louie, M. W., Bajdich, M., Sanwald, K. E., Cai, Y., Wise, A. M., Cheng, M.-J., Sokaras, D., Weng, T.-C., Alonso-Mori, R., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511559d · Cited by 2,732
Recent Progress in Cobalt‐Based Heterogeneous Catalysts for Electrochemical Water Splitting
Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Self-citationBao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Metadata
- Authors
- Lee, S. W., Carlton, C., Risch, M., Surendranath, Y., Chen, S., Furutsuki, S., Yamada, A., Nocera, D. G., & Shao-Horn, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-08
- Volume
- 134
- Issue
- 41
- Pages
- 16959-16962
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2316994779
- Cited by
- 316
- References
- 3
- FWCI
- 10.08
- Type
- journal article
- Language
- en
- Open access
- closed
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