The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation
Open accessAbstract
A heterogeneous nickel catalyst for the selective hydrogenolysis of aryl ethers to arenes and alcohols generated without an added dative ligand is described. The catalyst is formed in situ from the well-defined soluble nickel precursor Ni(COD)(2) or Ni(CH(2)TMS)(2)(TMEDA) in the presence of a base additive, such as (t)BuONa. The catalyst selectively cleaves C(Ar)-O bonds in aryl ether models of lignin without hydrogenation of aromatic rings, and it operates at loadings down to 0.25 mol % at 1 bar of H(2) pressure. The selectivity of this catalyst for electronically varied aryl ethers differs from that of the homogeneous catalyst reported previously, implying that the two catalysts are distinct from each other.
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Cites
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Widegren, J. A., & Finke, R. G. (2003) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(02)00728-8 · Cited by 1,245
Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels
Serrano-Ruiz, J. C., & Dumesic, J. A. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00436g · Cited by 850
Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers
Sergeev, A. G., & Hartwig, J. F. (2011) · Science · doi:10.1126/science.1200437 · Cited by 844
Self-citationCrabtree, R. H. (2012) · Chemical Reviews · doi:10.1021/cr2002905 · Cited by 628
Wang, X., & Rinaldi, R. (2012) · ChemSusChem · doi:10.1002/cssc.201200040 · Cited by 402
Lignocellulose: A chewy problem
Sanderson, K. (2011) · Nature · doi:10.1038/474s012a · Cited by 401
Beech Lignin—Proposal of a Constitutional Scheme
Nimz, H. (1974) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197403131 · Cited by 378
The new forestry biofuels sector
Pu, Y., Zhang, D., Singh, P. M., & Ragauskas, A. J. (2008) · Biofuels, Bioproducts and Biorefining · doi:10.1002/bbb.48 · Cited by 270
Álvarez-Bercedo, P., & Martin, R. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106943q · Cited by 262
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
A Photochemical Strategy for Lignin Degradation at Room Temperature
Nguyen, J. D., Matsuura, B. S., & Stephenson, C. R. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113462 · Cited by 454
Ferrini, P., & Rinaldi, R. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403747 · Cited by 431
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
Deuss, P. J., Barta, K., & de Vries, J. G. (2014) · Catal. Sci. Technol. · doi:10.1039/c3cy01058a · Cited by 316
Metadata
- Authors
- Sergeev, A. G., Webb, J. D., & Hartwig, J. F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-12-07
- Volume
- 134
- Issue
- 50
- Pages
- 20226-20229
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1970418635
- Cited by
- 327
- References
- 11
- FWCI
- 13.71
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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