The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Conformational Locking by Design: Relating Strain Energy with Luminescence and Stability in Rigid Metal–Organic Frameworks
Abstract
Minimization of the torsional barrier for phenyl ring flipping in a metal-organic framework (MOF) based on the new ethynyl-extended octacarboxylate ligand H(8)TDPEPE leads to a fluorescent material with a near-dark state. Immobilization of the ligand in the rigid structure also unexpectedly causes significant strain. We used DFT calculations to estimate the ligand strain energies in our and all other topologically related materials and correlated these with empirical structural descriptors to derive general rules for trapping molecules in high-energy conformations within MOFs. These studies portend possible applications of MOFs for studying fundamental concepts related to conformational locking and its effects on molecular reactivity and chromophore photophysics.
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Cites
Hong, Y., Lam, J. W. Y., & Tang, B. Z. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15113d · Cited by 6,363
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Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Aggregation-induced emission: fundamental understanding and future developments
Chen, Y., Lam, J. W. Y., Kwok, R. T. K., Liu, B., & Tang, B. Z. (2019) · Materials Horizons · doi:10.1039/c8mh01331d · Cited by 891
Wei, Z., Gu, Z.-Y., Arvapally, R. K., Chen, Y.-P., McDougald, R. N., Ivy, J. F., Yakovenko, A. A., Feng, D., Omary, M. A., & Zhou, H.-C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5006866 · Cited by 657
Zhang, M., Feng, G., Song, Z., Zhou, Y.-P., Chao, H.-Y., Yuan, D., Tan, T. T. Y., Guo, Z., Hu, Z., Tang, B. Z., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502643p · Cited by 657
Metal–organic framework materials for light-harvesting and energy transfer
So, M. C., Wiederrecht, G. P., Mondloch, J. E., Hupp, J. T., & Farha, O. K. (2015) · Chemical Communications · doi:10.1039/c4cc09596k · Cited by 473
Piezofluorochromic Metal–Organic Framework: A Microscissor Lift
Zhang, Q., Su, J., Feng, D., Wei, Z., Zou, X., & Zhou, H.-C. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04695 · Cited by 272
Metadata
- Authors
- Shustova, N. B., Cozzolino, A. F., & Dincă, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-26
- Volume
- 134
- Issue
- 48
- Pages
- 19596-19599
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1982217718
- Cited by
- 204
- References
- 1
- FWCI
- 9.61
- Type
- journal article
- Language
- en
- Open access
- closed
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