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Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple
Abstract
We report the direct synthesis of powder Na3Ti2(PO4)3 together with its low-potential electrochemical performance and crystal structure elucidation for the reduced and oxidized phases. First-principles calculations at the density functional theory level have been performed to gain further insight into the electrochemistry of Ti(IV)/Ti(III) and Ti(III)/Ti(II) redox couples in these sodium superionic conductor (NASICON) compounds. Finally, we have validated the concept of full-titanium-based sodium ion cells through the assembly of symmetric cells involving Na3Ti2(PO4)3 as both positive and negative electrode materials operating at an average potential of 1.7 V.
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Cited by
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Palomares, V., Casas-Cabanas, M., Castillo-Martínez, E., Han, M. H., & Rojo, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41031e · Cited by 992
A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries
Wang, Y., Yu, X., Xu, S., Bai, J., Xiao, R., Hu, Y.-S., Li, H., Yang, X.-Q., Chen, L., & Huang, X. (2013) · Nature Communications · doi:10.1038/ncomms3365 · Cited by 616
Na 3 V 2 (PO 4 ) 3 @C core–shell nanocomposites for rechargeable sodium-ion batteries
Duan, W., Zhu, Z., Li, H., Hu, Z., Zhang, K., Cheng, F., & Chen, J. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta00106k · Cited by 411
Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries
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Metadata
- Authors
- Senguttuvan, P., Rousse, G., Arroyo y de Dompablo, M. E., Vezin, H., Tarascon, J.-M., & Palacín, M. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-05
- Volume
- 135
- Issue
- 10
- Pages
- 3897-3903
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2141943186
- Cited by
- 252
- References
- 0
- FWCI
- 15.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Senguttuvan, P., Rousse, G., Arroyo y de Dompablo, M. E., Vezin, H., Tarascon, J.-M., & Palacín, M. R. (2013). Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple. Journal of the American Chemical Society. https://doi.org/10.1021/ja311044t
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
