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Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4
Abstract
Lithium-ion-conducting solid electrolytes hold promise for enabling high-energy battery chemistries and circumventing safety issues of conventional lithium batteries. Achieving the combination of high ionic conductivity and a broad electrochemical window in solid electrolytes is a grand challenge for the synthesis of battery materials. Herein we show an enhancement of the room-temperature lithium-ion conductivity by 3 orders of magnitude through the creation of nanostructured Li(3)PS(4). This material has a wide electrochemical window (5 V) and superior chemical stability against lithium metal. The nanoporous structure of Li(3)PS(4) reconciles two vital effects that enhance the ionic conductivity: (1) the reduction of the dimensions to a nanometer-sized framework stabilizes the high-conduction β phase that occurs at elevated temperatures, and (2) the high surface-to-bulk ratio of nanoporous β-Li(3)PS(4) promotes surface conduction. Manipulating the ionic conductivity of solid electrolytes has far-reaching implications for materials design and synthesis in a broad range of applications, including batteries, fuel cells, sensors, photovoltaic systems, and so forth.
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Cited by
Designing solid-state electrolytes for safe, energy-dense batteries
Zhao, Q., Stalin, S., Zhao, C.-Z., & Archer, L. A. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0165-5 · Cited by 2,372
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Wang, Z., Dong, Y., Li, H., Zhao, Z., Bin Wu, H., Hao, C., Liu, S., Qiu, J., & Lou, X. W. (2014) · Nature Communications · doi:10.1038/ncomms6002 · Cited by 1,059
Progress of enhancing the safety of lithium ion battery from the electrolyte aspect
Wang, Q., Jiang, L., Yu, Y., & Sun, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2018.10.035 · Cited by 915
Chen, X., He, W., Ding, L.-X., Wang, S., & Wang, H. (2019) · Energy & Environmental Science · doi:10.1039/c8ee02617c · Cited by 486
Metadata
- Authors
- Liu, Z., Fu, W., Payzant, E. A., Yu, X., Wu, Z., Dudney, N. J., Kiggans, J., Hong, K., Rondinone, A. J., & Liang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-14
- Volume
- 135
- Issue
- 3
- Pages
- 975-978
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2078268106
- Cited by
- 879
- References
- 0
- FWCI
- 22.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Z., Fu, W., Payzant, E. A., Yu, X., Wu, Z., Dudney, N. J., Kiggans, J., Hong, K., Rondinone, A. J., & Liang, C. (2013). Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4. Journal of the American Chemical Society. https://doi.org/10.1021/ja3110895
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