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Stable Hydrogen Evolution from CdS-Modified CuGaSe2 Photoelectrode under Visible-Light Irradiation

Moriya, Makoto, Minegishi, Tsutomu, Kumagai, Hiromu, Katayama, Masao, Kubota, Jun, Domen, Kazunari·2013·Journal of the American Chemical Society

Abstract

The photoelectrochemical properties of CuGaSe2 modified by deposition of a thin CdS layer were investigated. The CdS layer formed a p-n junction on the surface of the electrode, improving its photoelectrochemical properties. There was an optimal CdS thickness because of the balance between the charge separation effect and light absorption by CdS. CdS-deposited CuGaSe2 showed high stability under the observed reaction conditions and evolved hydrogen continuously for more than 10 days.

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Authors
Moriya, M., Minegishi, T., Kumagai, H., Katayama, M., Kubota, J., & Domen, K.
Venue
Journal of the American Chemical Society
Published
2013-03-01
Volume
135
Issue
10
Pages
3733-3735
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2026283345
Cited by
315
References
0
FWCI
13.71
Type
journal article
Language
en
Open access
closed

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