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Effective Mercury Sorption by Thiol-Laced Metal–Organic Frameworks: in Strong Acid and the Vapor Phase
Abstract
Free-standing, accessible thiol (-SH) functions have been installed in robust, porous coordination networks to provide wide-ranging reactivities and properties in the solid state. The frameworks were assembled by reacting ZrCl4 or AlCl3 with 2,5-dimercapto-1,4-benzenedicarboxylic acid (H2DMBD), which features the hard carboxyl and soft thiol functions. The resultant Zr-DMBD and Al-DMBD frameworks exhibit the UiO-66 and CAU-1 topologies, respectively, with the carboxyl bonded to the hard Zr(IV) or Al(III) center and the thiol groups decorating the pores. The thiol-laced Zr-DMBD crystals lower the Hg(II) concentration in water below 0.01 ppm and effectively take up Hg from the vapor phase. The Zr-DMBD solid also features a nearly white photoluminescence that is distinctly quenched after Hg uptake. The carboxyl/thiol combination thus illustrates the wider applicability of the hard-and-soft strategy for functional frameworks.
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Citations
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Metal–organic frameworks for heavy metal removal from water
Kobielska, P. A., Howarth, A. J., Farha, O. K., & Nayak, S. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.12.010 · Cited by 1,014
A versatile MOF-based trap for heavy metal ion capture and dispersion
Peng, Y., Huang, H., Zhang, Y., Kang, C., Chen, S., Song, L., Liu, D., & Zhong, C. (2018) · Nature Communications · doi:10.1038/s41467-017-02600-2 · Cited by 804
Mercury nano-trap for effective and efficient removal of mercury(II) from aqueous solution
Li, B., Zhang, Y., Ma, D., Shi, Z., & Ma, S. (2014) · Nature Communications · doi:10.1038/ncomms6537 · Cited by 587
Application of Lignin and Its Derivatives in Adsorption of Heavy Metal Ions in Water: A Review
Ge, Y., & Li, Z. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b01345 · Cited by 553
Metadata
- Authors
- Yee, K.-K., Reimer, N., Liu, J., Cheng, S.-Y., Yiu, S.-M., Weber, J., Stock, N., & Xu, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-15
- Volume
- 135
- Issue
- 21
- Pages
- 7795-7798
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2044369290
- Cited by
- 562
- References
- 0
- FWCI
- 16.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yee, K.-K., Reimer, N., Liu, J., Cheng, S.-Y., Yiu, S.-M., Weber, J., Stock, N., & Xu, Z. (2013). Effective Mercury Sorption by Thiol-Laced Metal–Organic Frameworks: in Strong Acid and the Vapor Phase. Journal of the American Chemical Society. https://doi.org/10.1021/ja400212k
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