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Atomic Resolution Imaging of Grain Boundary Defects in Monolayer Chemical Vapor Deposition-Grown Hexagonal Boron Nitride
Abstract
Grain boundaries are observed and characterized in chemical vapor deposition-grown sheets of hexagonal boron nitride (h-BN) via ultra-high-resolution transmission electron microscopy at elevated temperature. Five- and seven-fold defects are readily observed along the grain boundary. Dynamics of strained regions and grain boundary defects are resolved. The defect structures and the resulting out-of-plane warping are consistent with recent theoretical model predictions for grain boundaries in h-BN.
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Citations
Cited by
Xie, J., Zhang, J., Li, S., Grote, F., Zhang, X., Zhang, H., Wang, R., Lei, Y., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408329q · Cited by 2,350
Polycrystalline graphene and other two-dimensional materials
Yazyev, O. V., & Chen, Y. P. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.166 · Cited by 502
Synthesis of large single-crystal hexagonal boron nitride grains on Cu–Ni alloy
Lu, G., Wu, T., Yuan, Q., Wang, H., Wang, H., Ding, F., Xie, X., & Jiang, M. (2015) · Nature Communications · doi:10.1038/ncomms7160 · Cited by 377
Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode
Xie, J., Liao, L., Gong, Y., Li, Y., Shi, F., Pei, A., Sun, J., Zhang, R., Kong, B., Subbaraman, R., et al. (2017) · Science Advances · doi:10.1126/sciadv.aao3170 · Cited by 308
Metadata
- Authors
- Gibb, A. L., Alem, N., Chen, J.-H., Erickson, K. J., Ciston, J., Gautam, A., Linck, M., & Zettl, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-30
- Volume
- 135
- Issue
- 18
- Pages
- 6758-6761
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2312370353
- Cited by
- 260
- References
- 0
- FWCI
- 10.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gibb, A. L., Alem, N., Chen, J.-H., Erickson, K. J., Ciston, J., Gautam, A., Linck, M., & Zettl, A. (2013). Atomic Resolution Imaging of Grain Boundary Defects in Monolayer Chemical Vapor Deposition-Grown Hexagonal Boron Nitride. Journal of the American Chemical Society. https://doi.org/10.1021/ja400637n
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