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A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H2 from Solar Energy
Abstract
An unprecedented air-stable, nanospheric polyhydrido copper cluster, [Cu20H11(S2P(O(i)Pr)2)9] (1H), which is the first example of an elongated triangular orthobicupola array of Cu atoms having C3h symmetry, was synthesized and characterized. Its composition was primarily determined by electrospray ionization mass spectrometry, and it was fully characterized by (1)H, (2)H, and (31)P NMR spectroscopy and single-crystal X-ray diffraction (XRD). The structure of complex 1H can be expressed in terms of a trigonal-bipyramidal [Cu2H5](3-) unit anchored within an elongated triangular orthobicupola containing 18 Cu atoms, which is further stabilized by 18 S atoms from nine dithiophosphate ligands and six capping hydrides. The positions of the 11 hydrides revealed by low temperature XRD were supported by a density functional theory investigation on the simplified model [Cu20H11(S2PH2)9] with C3h symmetry. 1H is capable of releasing H2 gas upon irradiation with sunlight, under mild thermal conditions (65 °C), or in the presence of acids at room temperature.
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Cites
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Cited by
Tang, Q., Lee, Y., Li, D.-Y., Choi, W., Liu, C. W., Lee, D., & Jiang, D.-E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05591 · Cited by 382
Self-citationAtomically precise copper nanoclusters and their applications
Liu, X., & Astruc, D. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.01.001 · Cited by 322
Chemical Flexibility of Atomically Precise Metal Clusters
Li, S., Li, N.-N., Dong, X.-Y., Zang, S.-Q., & Mak, T. C. W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00896 · Cited by 280
Metadata
- Authors
- Dhayal, R. S., Liao, J.-H., Lin, Y.-R., Liao, P.-K., Kahlal, S., Saillard, J.-Y., & Liu, C. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-03-14
- Volume
- 135
- Issue
- 12
- Pages
- 4704-4707
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2321452580
- Cited by
- 171
- References
- 1
- FWCI
- 6.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dhayal, R. S., Liao, J.-H., Lin, Y.-R., Liao, P.-K., Kahlal, S., Saillard, J.-Y., & Liu, C. W. (2013). A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H2 from Solar Energy. Journal of the American Chemical Society. https://doi.org/10.1021/ja401576s
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