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The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction

Zhu, Huiyuan, Zhang, Sen, Guo, Shaojun, Su, Dong, Sun, Shouheng·2013·Journal of the American Chemical Society

Abstract

To further enhance the catalytic activity and durability of nanocatalysts for the oxygen reduction reaction (ORR), we synthesized a new class of 20 nm × 2 nm ternary alloy FePtM (M = Cu, Ni) nanorods (NRs) with controlled compositions. Supported on carbon support and treated with acetic acid as well as electrochemical etching, these FePtM NRs were converted into core/shell FePtM/Pt NRs. These core/shell NRs, especially FePtCu/Pt NRs, exhibited much improved ORR activity and durability. The Fe10Pt75Cu15 NRs showed a mass current densities of 1.034 A/mgPt at 512 mV vs Ag/AgCl and 0.222 A/mgPt at 557 mV vs Ag/AgCl, which are much higher than those for a commercial Pt catalyst (0.138 and 0.035 A/mgPt, respectively). Our controlled synthesis provides a general approach to core/shell NRs with enhanced catalysis for the ORR or other chemical reactions.

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Metadata

Authors
Zhu, H., Zhang, S., Guo, S., Su, D., & Sun, S.
Venue
Journal of the American Chemical Society
Published
2013-05-02
Volume
135
Issue
19
Pages
7130-7133
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1969281890
Cited by
263
References
4
FWCI
15.51
Type
journal article
Language
en
Open access
closed

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