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Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
Abstract
The catalytic activity of the zirconium terephthalate UiO-66(Zr) can be drastically increased by using a modulation approach. The combined use of trifluoroacetic acid and HCl during the synthesis results in a highly crystalline material, with partial substitution of terephthalates by trifluoroacetate. Thermal activation of the material leads not only to dehydroxylation of the hexanuclear Zr cluster but also to post-synthetic removal of the trifluoroacetate groups, resulting in a more open framework with a large number of open sites. Consequently, the material is a highly active catalyst for several Lewis acid catalyzed reactions.
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Citations
Cited by
Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Yuan, S., Qin, J.-S., Lollar, C. T., & Zhou, H.-C. (2018) · ACS Central Science · doi:10.1021/acscentsci.8b00073 · Cited by 561
Zhu, X., Li, B., Yang, J., Li, Y., Zhao, W., Shi, J., & Gu, J. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am5059074 · Cited by 486
The application of different typological and structural MOFs-based materials for the dyes adsorption
Jiang, D., Chen, M., Wang, H., Zeng, G., Huang, D., Cheng, M., Liu, Y., Xue, W., & Wang, Z. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.11.002 · Cited by 435
Chen, Y.-Z., Zhou, Y.-X., Wang, H., Lu, J., Uchida, T., Xu, Q., Yu, S.-H., & Jiang, H.-L. (2015) · ACS Catalysis · doi:10.1021/cs501953d · Cited by 423
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Rieth, A. J., Wright, A. M., & Dincă, M. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0140-1 · Cited by 402
Metadata
- Authors
- Vermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., Kirschhock, C., & De Vos, D. E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-26
- Volume
- 135
- Issue
- 31
- Pages
- 11465-11468
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2333547949
- Cited by
- 1,110
- References
- 0
- FWCI
- 32.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Vermoortele, F., Bueken, B., Le Bars, G., Van de Voorde, B., Vandichel, M., Houthoofd, K., Vimont, A., Daturi, M., Waroquier, M., Van Speybroeck, V., Kirschhock, C., & De Vos, D. E. (2013). Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr). Journal of the American Chemical Society. https://doi.org/10.1021/ja405078u
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