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Pt@CeO2 Multicore@Shell Self-Assembled Nanospheres: Clean Synthesis, Structure Optimization, and Catalytic Applications
Abstract
A clean nonorganic synthetic method has been developed to fabricate the uniform pomegranate-like Pt@CeO2 multicore@shell nanospheres in a large scale. Under the effective protection of Ar atmosphere the redox reaction just simply happened between Ce(NO3)3 and K2PtCl4 in an alkaline aqueous solution, in which no other reducing agents or surfactants were added. The as-obtained nanospheres exhibited excellent structure stability even being calcined at 600 °C for 5 h. Moreover, the as-obtained Pt@CeO2 multicore@shell nanospheres can be further supported on reduced graphene oxide (RGO) to form heterogeneous nanocatalyst, which has been successfully applied in the chemical reduction reaction of nitrophenol (NP) by ammonia borane (NH3BH3, dubbed as AB) instead of hazardous H2 or NaBH4.
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Cites
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Cited by
Encapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts
Zhan, W.-W., Zhu, Q.-L., & Xu, Q. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02209 · Cited by 481
Sintering-resistant Pt@CeO 2 nanoparticles for high-temperature oxidation catalysis
Lee, S., Seo, J., & Jung, W. (2016) · Nanoscale · doi:10.1039/c6nr00170j · Cited by 94
Cao, Y., Tang, M., Li, M., Deng, J., Xu, F., Xie, L., & Wang, Y. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b01853 · Cited by 62
Wei, Q., Qiu, S., Yin, C., Liu, J., Xia, Y., Wen, X., Zou, Y., Xu, F., Sun, L., & Chu, H. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.166207 · Cited by 55
Metadata
- Authors
- Wang, X., Liu, D., Song, S., & Zhang, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-14
- Volume
- 135
- Issue
- 42
- Pages
- 15864-15872
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2012364595
- Cited by
- 341
- References
- 1
- FWCI
- 18.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, X., Liu, D., Song, S., & Zhang, H. (2013). Pt@CeO2 Multicore@Shell Self-Assembled Nanospheres: Clean Synthesis, Structure Optimization, and Catalytic Applications. Journal of the American Chemical Society. https://doi.org/10.1021/ja4069134
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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