The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation
Abstract
We describe the synthesis of a cobalt(I)-N2 complex (2) supported by a meridional bis-phosphino-boryl (PBP) ligand. Complex 2 undergoes a clean reaction with 2 equiv of dihydrogen to afford a dihydridoboratocobalt dihydride (3). The ability of boron to switch between a boryl and a dihydridoborate conformation makes possible the reversible conversion of 2 and 3. Complex 3 reacts with HMe2N-BH3 to give a hydridoborane cobalt tetrahydridoborate complex. We explore this boryl-cobalt system in the context of catalytic olefin hydrogenation as well as amine-borane dehydrogenation/transfer hydrogenation.
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Cites
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
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Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen Storage
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Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation
Monfette, S., Turner, Z. R., Semproni, S. P., & Chirik, P. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300503k · Cited by 345
Mild and Homogeneous Cobalt‐Catalyzed Hydrogenation of CC, CO, and CN Bonds
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Coordination and Dehydrogenation of Amine–Boranes at Metal Centers
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Homogeneous, Titanocene-Catalyzed Dehydrocoupling of Amine−Borane Adducts
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Cited by
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
Alig, L., Fritz, M., & Schneider, S. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00555 · Cited by 887
Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides
Rossin, A., & Peruzzini, M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00043 · Cited by 421
Metadata
- Authors
- Lin, T.-P., & Peters, J. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-07
- Volume
- 135
- Issue
- 41
- Pages
- 15310-15313
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2122315740
- Cited by
- 255
- References
- 19
- FWCI
- 11.00
- Type
- journal article
- Language
- en
- Open access
- closed
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