The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Electronic Chemical Potentials of Porous Metal–Organic Frameworks
Open accessAbstract
The binding energy of an electron in a material is a fundamental characteristic, which determines a wealth of important chemical and physical properties. For metal-organic frameworks this quantity is hitherto unknown. We present a general approach for determining the vacuum level of porous metal-organic frameworks and apply it to obtain the first ionization energy for six prototype materials including zeolitic, covalent, and ionic frameworks. This approach for valence band alignment can explain observations relating to the electrochemical, optical, and electrical properties of porous frameworks.
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Cites
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Self-citation
Cited by
Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
Wang, X., Chen, L., Chong, S. Y., Little, M. A., Wu, Y., Zhu, W.-H., Clowes, R., Yan, Y., Zwijnenburg, M. A., Sprick, R. S., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0141-5 · Cited by 1,320
Interplay of Orbital and Relativistic Effects in Bismuth Oxyhalides: BiOF, BiOCl, BiOBr, and BiOI
Ganose, A. M., Cuff, M., Butler, K. T., Walsh, A., & Scanlon, D. O. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00349 · Cited by 426
Self-citationYan, Y., Li, C., Wu, Y., Gao, J., & Zhang, Q. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta03749d · Cited by 260
Structural diversity of alkaline-earth 2,5-thiophenedicarboxylates
Balendra, & Ramanan, A. (2017) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2016.11.029 · Cited by 16
Metadata
- Authors
- Butler, K. T., Hendon, C. H., & Walsh, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-06
- Volume
- 136
- Issue
- 7
- Pages
- 2703-2706
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2154769994
- Cited by
- 293
- References
- 34
- FWCI
- 13.26
- Type
- journal article
- Language
- en
- Open access
- hybrid
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