A New Microporous Zeolitic Silicoborate (ITQ-52) with Interconnected Small and Medium Pores
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A new zeolite (named as ITQ-52) having large cavities and small and medium channels has been synthesized. This was achieved by using a new family of amino-phosphonium cations as organic structure directing agents (OSDA). These cations contain P-C and P-N bonds, and therefore they lie between previously reported P-containing OSDA, such as tetraalkylphosphonium and phosphazenes. In this study, it has been found that 1,4-butanediylbis[tris(dimethylamino)]phosphonium dication is a very efficient OSDA for crystallization of several zeolites, and in some particular conditions, the new zeolite ITQ-52 was synthesized as a pure phase. The structure of ITQ-52 has been solved using high-resolution synchrotron X-ray powder diffraction data of the calcined solid. This new zeolite crystallizes in the space group I2/m, with cell parameters a = 17.511 Å, b = 17.907 Å, c = 12.367 Å, and β = 90.22°. The topology of ITQ-52 can be described as a replication of a composite building unit with ring notation [4(3)5(4)6(1)] that gives rise to the formation of an interconnected 8R and 10R channel system.
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B-silicate zeolites are often produced with different structures than Al-substituted zeolites.
“Importantly, very often, B-silicate zeolites are produced with different structures than Al-substituted zeolites.62−65”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [64]
Cites
The ITQ-37 mesoporous chiral zeolite
Sun, J., Bonneau, C., Cantín, Á., Corma, A., Díaz-Cabañas, M. J., Moliner, M., Zhang, D., Li, M., & Zou, X. (2009) · Nature · doi:10.1038/nature07957 · Cited by 581 · see citing works
Self-citationTranslating new materials discoveries in zeolite research to commercial manufacture
Zones, S. I. (2011) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2011.03.039 · Cited by 227 · see citing works
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Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126 · see citing works
Self-citationThe ADOR mechanism for the synthesis of new zeolites
Eliášová, P., Opanasenko, M., Wheatley, P. S., Shamzhy, M., Mazur, M., Nachtigall, P., Roth, W. J., Morris, R. E., & Čejka, J. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00045a · Cited by 340 · see citing works
Guo, P., Strohmaier, K., Vroman, H., Afeworki, M., Ravikovitch, P. I., Paur, C. S., Sun, J., Burton, A., & Zou, X. (2016) · Inorganic Chemistry Frontiers · doi:10.1039/c6qi00262e · Cited by 29 · see citing works
- Authors
- Simancas, R., Jordá, J. L., Rey, F., Corma, A., Cantín, A., Peral, I., & Popescu, C.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia−Consejo Superior de Investigaciones Científicas, Av. de los Naranjos s/n, 46022 Valencia, Spain
- ALBA Synchrotron (Spain) (ES)
- ALBA Light Source, Cerdanyola del Vallés, Barcelona, Spain
- Corresponding author
- Rey, Fernando
- Corma, Avelino
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-19
- Volume
- 136
- Issue
- 9
- Pages
- 3342-3345
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2322753666
- Cited by
- 60
- References
- 2
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 1 · 2023: 3 · 2022: 9 · 2021: 6 · 2020: 3 · 2019: 4 · 2018: 3 · 2017: 8 · 2016: 6 · 2015: 11 · 2014: 4
- FWCI
- 4.11
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- cc-by-nc-nd
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- RiuNet (Universitat Politècnica de València) (submittedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Keywords
- zeolite synthesis, microporous materials, organic structure-directing agents, zeolite crystal structure, zeolite topology
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