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Homogeneous Perdehydrogenation and Perhydrogenation of Fused Bicyclic N-Heterocycles Catalyzed by Iridium Complexes Bearing a Functional Bipyridonate Ligand
Abstract
Homogeneous perdehydrogenation of saturated bicyclic 2,6-dimethyldecahydro-1,5-naphthyridine and perhydrogenation of aromatic 2,6-dimethyl-1,5-naphthyridine with release and uptake of five molecules of H2 are efficiently achieved by iridium complexes bearing a functional bipyridonate ligand. Successive perhydrogenation and perdehydrogenation of 2,6-dimethyl-1,5-naphthryridine using a single iridium complex also proceed with the reversible interconversion of the catalytic species, depending on the presence or absence of H2.
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Citations
Cited by
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Aakko-Saksa, P. T., Cook, C., Kiviaho, J., & Repo, T. (2018) · Journal of Power Sources · doi:10.1016/j.jpowsour.2018.04.011 · Cited by 533
Makepeace, J. W., He, T., Weidenthaler, C., Jensen, T. R., Chang, F., Vegge, T., Ngene, P., Kojima, Y., de Jongh, P. E., Chen, P., et al. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.01.144 · Cited by 285
Xu, R., Chakraborty, S., Yuan, H., & Jones, W. D. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02002 · Cited by 266
Metadata
- Authors
- Fujita, K.-I., Tanaka, Y., Kobayashi, M., & Yamaguchi, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-24
- Volume
- 136
- Issue
- 13
- Pages
- 4829-4832
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2147843383
- Cited by
- 268
- References
- 0
- FWCI
- 13.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Homogeneous Perdehydrogenation and Perhydrogenation of Fused Bicyclic N-Heterocycles Catalyzed by Iridium Complexes Bearing a Functional Bipyridonate Ligand. https://app.cochat.ai/papers/10.1021/ja5001888
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- Fujita, K.-I., Tanaka, Y., Kobayashi, M., & Yamaguchi, R. (2014). Homogeneous Perdehydrogenation and Perhydrogenation of Fused Bicyclic N-Heterocycles Catalyzed by Iridium Complexes Bearing a Functional Bipyridonate Ligand. Journal of the American Chemical Society. https://doi.org/10.1021/ja5001888
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